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Title: KKR calculation of the electronic structure of cubic WO/sub 3/ and NaWO/sub 3/

Abstract

Explanation of the metallic properties of the sodium tungsten bronzes has provoked considerable controversy. The main point of contention has concerned which atomic orbitals constitute the conduction band. At least five models have been proposed. These have involved the tungsten 6s states (2), sodium 3p states (3), tungsten 5d (t/sub 2g/) states (4), sodium states (5), and a covalent admixture of oxygen 2p/sub ..pi../ and tungsten 5d (t/sub 2g/) states (6) in the conduction process.

Authors:
Publication Date:
Research Org.:
Ames Lab., IA (USA)
OSTI Identifier:
6607716
Report Number(s):
IS-T-943
TRN: 81-006164
DOE Contract Number:  
W-7405-ENG-82
Resource Type:
Technical Report
Resource Relation:
Other Information: Thesis
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; SODIUM TUNGSTEN BRONZE; ELECTRONIC STRUCTURE; TUNGSTEN OXIDES; ALKALI METAL COMPOUNDS; CHALCOGENIDES; OXIDES; OXYGEN COMPOUNDS; SODIUM COMPOUNDS; SODIUM OXIDES; TRANSITION ELEMENT COMPOUNDS; TUNGSTEN COMPOUNDS; 360102* - Metals & Alloys- Structure & Phase Studies

Citation Formats

Kopp, L. KKR calculation of the electronic structure of cubic WO/sub 3/ and NaWO/sub 3/. United States: N. p., 1981. Web.
Kopp, L. KKR calculation of the electronic structure of cubic WO/sub 3/ and NaWO/sub 3/. United States.
Kopp, L. Sun . "KKR calculation of the electronic structure of cubic WO/sub 3/ and NaWO/sub 3/". United States.
@article{osti_6607716,
title = {KKR calculation of the electronic structure of cubic WO/sub 3/ and NaWO/sub 3/},
author = {Kopp, L},
abstractNote = {Explanation of the metallic properties of the sodium tungsten bronzes has provoked considerable controversy. The main point of contention has concerned which atomic orbitals constitute the conduction band. At least five models have been proposed. These have involved the tungsten 6s states (2), sodium 3p states (3), tungsten 5d (t/sub 2g/) states (4), sodium states (5), and a covalent admixture of oxygen 2p/sub ..pi../ and tungsten 5d (t/sub 2g/) states (6) in the conduction process.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1981},
month = {2}
}

Technical Report:
Other availability
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