Tritium/protium discrimination in reduction of cyclopropenium ion by sodium borohydride does not identify the rate-determining step
Journal Article
·
· J. Org. Chem.; (United States)
- Univ. of Costa Rica, San Jose
Intramolecular isotope discrimination vitiates an attempt to deduce from the observation of a tritium isotope effect in borohydride reduction of a cyclopropenium ion that hydride transfer is at least partially rate determining.
- OSTI ID:
- 6603759
- Journal Information:
- J. Org. Chem.; (United States), Vol. 46:3
- Country of Publication:
- United States
- Language:
- English
Similar Records
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Fri Jun 20 00:00:00 EDT 1980
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OSTI ID:6603759
Determination of the specific activity of high specific activity tritium labeled sodium borohydride by tritium nuclear magnetic resonance spectrometry
Journal Article
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Journal Article
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· J. Am. Chem. Soc.; (United States)
·
OSTI ID:6603759
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
TRITIUM
ISOTOPE EFFECTS
BOROHYDRIDES
CHEMICAL REACTION KINETICS
CYCLOALKENES
REDUCTION
SODIUM COMPOUNDS
TRITIUM COMPOUNDS
ALKALI METAL COMPOUNDS
ALKENES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BORON COMPOUNDS
CHEMICAL REACTIONS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
KINETICS
LABELLED COMPOUNDS
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
RADIOISOTOPES
REACTION KINETICS
YEARS LIVING RADIOISOTOPES
400302* - Organic Chemistry- Isotope Effects- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
TRITIUM
ISOTOPE EFFECTS
BOROHYDRIDES
CHEMICAL REACTION KINETICS
CYCLOALKENES
REDUCTION
SODIUM COMPOUNDS
TRITIUM COMPOUNDS
ALKALI METAL COMPOUNDS
ALKENES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BORON COMPOUNDS
CHEMICAL REACTIONS
HYDROCARBONS
HYDROGEN COMPOUNDS
HYDROGEN ISOTOPES
ISOTOPES
KINETICS
LABELLED COMPOUNDS
LIGHT NUCLEI
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
RADIOISOTOPES
REACTION KINETICS
YEARS LIVING RADIOISOTOPES
400302* - Organic Chemistry- Isotope Effects- (-1987)