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Title: Circular dichroism of Eu/sup 3 +/ and Nd/sup 3 +/ in a K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ single crystal

Abstract

The low-resolution circular dichroism in (CD) and absorption spectra of doped Nd/sup 3 +/ crystals primarily with a view to verify the expectations regarding low-resolution lanthanide optical activity is presented. In order to compare the CD of the Nd/sup 3 +/ transition, which are commonly considered as electric-dipole allowed, with that of primarily magnetic-dipole-allowed Eu/sup 3 +/ transitions having an identical environment, we have grown and studied a single crystal of K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ with Eu/sup 3 +/ as dopant.

Authors:
;
Publication Date:
Research Org.:
Indian Association for the Cultivation of Science, Calcutta, India
OSTI Identifier:
6577361
Resource Type:
Journal Article
Journal Name:
Inorg. Chem.; (United States)
Additional Journal Information:
Journal Volume: 21:6
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; EUROPIUM COMPOUNDS; DICHROISM; NEODYMIUM COMPOUNDS; CATIONS; CRYSTAL DOPING; EXPERIMENTAL DATA; MAGNETIC DIPOLE MOMENTS; NITROGEN OXIDES; POTASSIUM COMPOUNDS; RARE EARTH COMPLEXES; SPECTRA; ALKALI METAL COMPOUNDS; CHALCOGENIDES; CHARGED PARTICLES; COMPLEXES; DATA; DIPOLE MOMENTS; INFORMATION; IONS; MAGNETIC MOMENTS; NITROGEN COMPOUNDS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; RARE EARTH COMPOUNDS; 400104* - Spectral Procedures- (-1987)

Citation Formats

Chatterjee, P K, and Chowdhury, M. Circular dichroism of Eu/sup 3 +/ and Nd/sup 3 +/ in a K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ single crystal. United States: N. p., 1982. Web. doi:10.1021/ic00136a076.
Chatterjee, P K, & Chowdhury, M. Circular dichroism of Eu/sup 3 +/ and Nd/sup 3 +/ in a K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ single crystal. United States. doi:10.1021/ic00136a076.
Chatterjee, P K, and Chowdhury, M. Tue . "Circular dichroism of Eu/sup 3 +/ and Nd/sup 3 +/ in a K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ single crystal". United States. doi:10.1021/ic00136a076.
@article{osti_6577361,
title = {Circular dichroism of Eu/sup 3 +/ and Nd/sup 3 +/ in a K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ single crystal},
author = {Chatterjee, P K and Chowdhury, M},
abstractNote = {The low-resolution circular dichroism in (CD) and absorption spectra of doped Nd/sup 3 +/ crystals primarily with a view to verify the expectations regarding low-resolution lanthanide optical activity is presented. In order to compare the CD of the Nd/sup 3 +/ transition, which are commonly considered as electric-dipole allowed, with that of primarily magnetic-dipole-allowed Eu/sup 3 +/ transitions having an identical environment, we have grown and studied a single crystal of K/sub 3/Nd/sub 2/(NO/sub 3/)/sub 9/ with Eu/sup 3 +/ as dopant.},
doi = {10.1021/ic00136a076},
journal = {Inorg. Chem.; (United States)},
number = ,
volume = 21:6,
place = {United States},
year = {1982},
month = {6}
}