Crystal and molecular structure of hydridotris(bis(trimethylsilyl)amido)uranium (IV)

Journal Article · Sun Feb 01 00:00:00 EST 1981 · Inorg. Chem.; (United States)

DOI:https://doi.org/10.1021/ic50216a058· OSTI ID:6570338

Andersen, R A; Zalkin, A; Templeton, D H

New hydride derivatives of thorium(IV) and uranium(IV), HM(N(SiMe/sub 3/)/sub 2/)/sub 3/, have been prepared recently. This paper describes the crystal structure of the uranium species, though the hydride ion was not located, and shows that the thorium analogue is isostructural. The reaction chemistry and spectroscopy show that these derivatives are authentic examples of four-coordinate, monomeric hydride, compounds.

• Research Organization: Lawrence Berkeley Lab., CA
• DOE Contract Number: W-7405-ENG-48
• OSTI ID: 6570338
• Journal Information: Inorg. Chem.; (United States), Vol. 20:2
• Country of Publication: United States
• Language: English

Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
THORIUM COMPLEXES
MOLECULAR STRUCTURE
URANIUM COMPLEXES
CHEMICAL PREPARATION
CHEMICAL PROPERTIES
CRYSTAL STRUCTURE
ORGANIC NITROGEN COMPOUNDS
SILANES
SPECTRA
ACTINIDE COMPLEXES
COMPLEXES
HYDRIDES
HYDROGEN COMPOUNDS
ORGANIC COMPOUNDS
SILICON COMPOUNDS
SYNTHESIS
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials