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Title: Research in chemical kinetics. Annual report, 1993

Abstract

Progress on the seven projects under this contract is reported. The projects are: (1) Chlorine atom reactions with vinyl bromide. Mass spectrometric investigations of the anti-Markownikoff rule. (2) Chlorine atom reactions with CF{sub 2}{double_bond}CFBr. (3) Gas phase thermal {sup 38}Cl reactions with (CH{sub 2}{double_bond}CH){sub n}M (M=Sn, Si, n=4; M=Sb, n=3; M=Hg, n=2). (4) Gas phase reactions of thermal chlorine atoms with (CH{sub 3}){sub 4}M (M=C, Si, Ge, Sn, Pb). (5) Hydrogen abstraction reactions by thermal chlorine atoms with HFCs, HCFCs, and halomethanes. (6) Half-stabilization pressure of chlorine atoms plus ethylene in a nitrogen bath. (7) {sup 14}C content of atmospheric OCS, C{sub 2}H{sub 6} and C{sub 3}H{sub 8}.

Authors:
Publication Date:
Research Org.:
Univ. of California, Dept. of Chemistry, Irvine, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Research, Washington, DC (United States)
OSTI Identifier:
656622
Report Number(s):
DOE/ER/13469-T9
ON: DE98006356; BR: KC0301010; TRN: AHC29817%%178
DOE Contract Number:  
FG03-86ER13469
Resource Type:
Technical Report
Resource Relation:
Other Information: PBD: [1993]
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; PROGRESS REPORT; CHEMICAL REACTION KINETICS; ATMOSPHERIC CHEMISTRY; CHLORINE; FLUORINATED ALIPHATIC HYDROCARBONS; ORGANOMETALLIC COMPOUNDS; REFRIGERANTS; CARBON OXYSULFIDE; ETHANE; PROPANE; CARBON 14; CHLORINE 38; EXPERIMENTAL DATA

Citation Formats

Rowland, F.S. Research in chemical kinetics. Annual report, 1993. United States: N. p., 1993. Web. doi:10.2172/656622.
Rowland, F.S. Research in chemical kinetics. Annual report, 1993. United States. doi:10.2172/656622.
Rowland, F.S. Fri . "Research in chemical kinetics. Annual report, 1993". United States. doi:10.2172/656622. https://www.osti.gov/servlets/purl/656622.
@article{osti_656622,
title = {Research in chemical kinetics. Annual report, 1993},
author = {Rowland, F.S.},
abstractNote = {Progress on the seven projects under this contract is reported. The projects are: (1) Chlorine atom reactions with vinyl bromide. Mass spectrometric investigations of the anti-Markownikoff rule. (2) Chlorine atom reactions with CF{sub 2}{double_bond}CFBr. (3) Gas phase thermal {sup 38}Cl reactions with (CH{sub 2}{double_bond}CH){sub n}M (M=Sn, Si, n=4; M=Sb, n=3; M=Hg, n=2). (4) Gas phase reactions of thermal chlorine atoms with (CH{sub 3}){sub 4}M (M=C, Si, Ge, Sn, Pb). (5) Hydrogen abstraction reactions by thermal chlorine atoms with HFCs, HCFCs, and halomethanes. (6) Half-stabilization pressure of chlorine atoms plus ethylene in a nitrogen bath. (7) {sup 14}C content of atmospheric OCS, C{sub 2}H{sub 6} and C{sub 3}H{sub 8}.},
doi = {10.2172/656622},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Fri Dec 31 00:00:00 EST 1993},
month = {Fri Dec 31 00:00:00 EST 1993}
}

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