Radiochemical study of reaction of free butyl cations with benzene in gas and condensed media

Journal Article · · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:6550085

Nefedov, V D; Sinotova, E N; Arkhipov, Yu M; Gomzina, N A

Ion-molecular reactions between free butyl cations obtained by nucleochemical technique and benzene in the gas, liquid, and solid phases have been studied. It has been proved that the main products of ion-molecular reaction of free butyl cations and benzene are isomeric n-, sec-, and tert-butyl benzenes in the gas phase and only n- and sec-butyl benzenes in the condensed media. An explanation has been offered for the probable processes giving the observed products.

• OSTI ID: 6550085
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Vol. 25:4; Other Information: Translated from Radiokhimiya (USSR); 25: No. 4, 557-561(Jul-Aug 1983)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BENZENE
CHEMICAL REACTIONS
BUTANE
CATIONS
GASES
LIQUIDS
RADIOCHEMICAL ANALYSIS
SOLIDS
ALKANES
AROMATICS
CHARGED PARTICLES
CHEMICAL ANALYSIS
FLUIDS
HYDROCARBONS
IONS
ORGANIC COMPOUNDS
QUANTITATIVE CHEMICAL ANALYSIS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)