Thermodynamic and transport properties of aqueous and molten electrolytes
This book examines the physical chemistry of electrolytes in solution and in the molten state. Topics considered include ionic solvation (solvents, thermodynamic and transport properties, spectroscopic and diffraction methods, theoretical aspects of solvation), ionic interactions and activity behavior of electrolyte solutions (the Debye-Hueckel evaluation of the activity coefficient of an electrolyte in solution, statistical-mechanical treatments of ionic interactions in solution, ion-solvent interactions in the activity behavior of electrolytes, short-range ionic interactions), the conductance of electrolyte solutions (the basis of the Onsager approach, the boundary conditions, differential equations for two-particle distribution functions, recent developments in conductance, transference numbers, ionic limiting mobilities, the conductance of mixtures of electrolytes, optimization in measurements and data processing), proton solvation and proton transfer in chemical and electrochemical processes (proton solvation and characterization of the H/sub 3/O/sup +/ ion, proton transfer in chemical ionization processes in solution, continuous proton transfer in conductance processes, proton transfer in electrode processes), and the structure and thermodynamics of molten salts (molten salts as liquids, single salts, salt mixtures). Nonaqueous solutions are not covered in this volume.
- OSTI ID:
- 6491636
- Resource Relation:
- Related Information: Comprehensive treatise of electrochemistry, Vol. 5
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AQUEOUS SOLUTIONS
ELECTROCHEMISTRY
THERMODYNAMICS
ELECTROLYTES
SOLVATION
BOUNDARY CONDITIONS
DATA PROCESSING
DIFFERENTIAL EQUATIONS
DIFFRACTION METHODS
DISTRIBUTION FUNCTIONS
ELECTRIC CONDUCTIVITY
ELECTRODES
ION MOBILITY
IONIZATION
IONS
MIXTURES
MOLTEN SALTS
ONSAGER RELATIONS
OPTIMIZATION
OXONIUM IONS
PROTON TRANSPORT
SOLVENTS
SPECTROSCOPY
STATISTICS
CHARGED PARTICLES
CHARGED-PARTICLE TRANSPORT
CHEMISTRY
DISPERSIONS
ELECTRICAL PROPERTIES
EQUATIONS
FUNCTIONS
MATHEMATICS
MOBILITY
MOLECULAR IONS
PARTICLE MOBILITY
PHYSICAL PROPERTIES
PROCESSING
RADIATION TRANSPORT
SALTS
SOLUTIONS
400400* - Electrochemistry