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Title: Fundamental insights on impact of non-condensible gas evolution from coating pyrolysis and intentional injection on molten-aluminum water explosion onset during direct-chill casting

Conference ·
OSTI ID:645518
;  [1];  [2]
  1. Oak Ridge National Lab., TN (United States)
  2. Oak Ridge Associated Universities, TN (United States)

Explosive interactions between molten aluminum and water are being studied with a focus on fundamentals to determine what causes robust-enough triggers for explosion onset, to determine the extent of protection provided from various coatings and to develop a fundamentally-based simple, cost-effective novel methodology for prevention. The workscope includes experimentation and mathematical modeling of the interactions between molten metals and water at various different coated and uncoated surfaces. Phenomenological issues related to surface wettability, gas generation from coatings, charring of coatings, inertial constraint, melt temperature, water temperature, external shocks are being investigated systematically to gage their relative impact on the triggerability of surface-assisted steam explosions. The steam explosion triggering studies (SETS) facility was designed and constructed as a rapid-turnaround, cost-effective, and safe means to address these phenomenological issues. Data from SETS tests have indicated that, non-condensible gas (NCG) generation during paint pyrolysis plays a predominant role in explosion prevention. This paper describes results of studies on impact of deliberate NCG injection on explosion prevention, via molten melt drops free-falling into water, as well as from tests using the SETS facility for studying entrapment induced explosive boiling. SETS is also being used to obtain information on time-varying and integral amounts of NCGs generated from various paints. Relevant data are presented. Results of investigations, taken together provide compelling evidence on the positive role NCGs play on explosion prevention.

Research Organization:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE Office of Energy Research, Washington, DC (United States); USDOE Assistant Secretary for Energy Efficiency and Renewable Energy, Washington, DC (United States)
DOE Contract Number:
AC05-84OR21400
OSTI ID:
645518
Report Number(s):
ORNL/CP-95318; CONF-980535-; ON: DE98001419; TRN: AHC2DT03%%59
Resource Relation:
Conference: 1998 casting congress, Atlanta, GA (United States), 1 May 1998; Other Information: PBD: 1 May 1998
Country of Publication:
United States
Language:
English