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Title: Catalytic oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts

Abstract

The great interest displayed lately in heterogeneous catalytic reactions of carbon dioxide is caused by two reasons: (1) the necessity to fight the greenhouse effect and (2) the exhaust of carbon raw material sources. Reactions of oxidative transformation of organic compounds of different classes (alkanes, alkenes, and alcohols) with a nontraditional oxidant, carbon dioxide, were studied on oxide catalysts Fe-O, Cr-O, Mn-O and on multicomponent systems based on manganese oxide. The supported manganese oxide catalysts are active, selective, and stable in conversion of the CH[sub 4] + CO[sub 2] mixture into synthesis gas and in oxidative dehydrogenation of C[sub 2] [minus] C[sub 7] hydrocarbons and the lower alcohols. Unlike metal catalysts manganese oxide based catalysts do not form a carbon layer during the reaction.

Authors:
 [1]; ;  [2]
  1. Russian Academy of Sciences, Moscow (Russian Federation). N.N. Semenov Inst. of Chemical Physics
  2. Azerbaijan Academy of Sciences, Telnova (Azerbaijan). Yu.G. Mamedaliev Inst. of Petrochemical Processes
Publication Date:
OSTI Identifier:
6448766
Resource Type:
Journal Article
Journal Name:
Industrial and Engineering Chemistry Research; (United States)
Additional Journal Information:
Journal Volume: 34:2; Journal ID: ISSN 0888-5885
Country of Publication:
United States
Language:
English
Subject:
54 ENVIRONMENTAL SCIENCES; 03 NATURAL GAS; 02 PETROLEUM; ALCOHOLS; DEHYDROGENATION; ALKANES; ALKENES; CARBON DIOXIDE; AIR POLLUTION CONTROL; REDUCTION; METHANE; OXIDATION; CATALYTIC EFFECTS; CHROMIUM OXIDES; IRON OXIDES; MANGANESE OXIDES; OXIDIZERS; CARBON COMPOUNDS; CARBON OXIDES; CHALCOGENIDES; CHEMICAL REACTIONS; CHROMIUM COMPOUNDS; CONTROL; HYDROCARBONS; HYDROXY COMPOUNDS; IRON COMPOUNDS; MANGANESE COMPOUNDS; ORGANIC COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; POLLUTION CONTROL; TRANSITION ELEMENT COMPOUNDS; 540120* - Environment, Atmospheric- Chemicals Monitoring & Transport- (1990-); 030400 - Natural Gas- Products & By-Products; 020500 - Petroleum- Products & By-Products

Citation Formats

Krylov, O V, Mamedov, A Kh, and Mirzabekova, S R. Catalytic oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts. United States: N. p., 1995. Web. doi:10.1021/ie00041a007.
Krylov, O V, Mamedov, A Kh, & Mirzabekova, S R. Catalytic oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts. United States. https://doi.org/10.1021/ie00041a007
Krylov, O V, Mamedov, A Kh, and Mirzabekova, S R. 1995. "Catalytic oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts". United States. https://doi.org/10.1021/ie00041a007.
@article{osti_6448766,
title = {Catalytic oxidation of hydrocarbons and alcohols by carbon dioxide on oxide catalysts},
author = {Krylov, O V and Mamedov, A Kh and Mirzabekova, S R},
abstractNote = {The great interest displayed lately in heterogeneous catalytic reactions of carbon dioxide is caused by two reasons: (1) the necessity to fight the greenhouse effect and (2) the exhaust of carbon raw material sources. Reactions of oxidative transformation of organic compounds of different classes (alkanes, alkenes, and alcohols) with a nontraditional oxidant, carbon dioxide, were studied on oxide catalysts Fe-O, Cr-O, Mn-O and on multicomponent systems based on manganese oxide. The supported manganese oxide catalysts are active, selective, and stable in conversion of the CH[sub 4] + CO[sub 2] mixture into synthesis gas and in oxidative dehydrogenation of C[sub 2] [minus] C[sub 7] hydrocarbons and the lower alcohols. Unlike metal catalysts manganese oxide based catalysts do not form a carbon layer during the reaction.},
doi = {10.1021/ie00041a007},
url = {https://www.osti.gov/biblio/6448766}, journal = {Industrial and Engineering Chemistry Research; (United States)},
issn = {0888-5885},
number = ,
volume = 34:2,
place = {United States},
year = {Wed Feb 01 00:00:00 EST 1995},
month = {Wed Feb 01 00:00:00 EST 1995}
}