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Title: Total organic carbon in streamwater from four long-term monitored catchments in Norway

Journal Article · · Environment International; (United States)
;  [1]
  1. Norwegian Institute for Water Research, Oslo (Norway)

Flux, concentration, and net charge of total organic carbon (TOC) have been related to different physico-chemical parameters present in air/precipitation and streamwater at four long-term monitored catchments in Norway, during the period 1986-1992. The catchments vary a lot with respect to annual water input, acid rain, and the streamwater concentration of TOC. Thus, relationships between concentration/NC of TOC and chemical compounds in precipitation and streamwater were often catchment-specific. However, seasonal climatic changes, like air temperature and hydrology, were found to be important for the concentration variations of TOC. Organic matter has an important role in weathering reactions in the catchment. The correlation between concentration of total aluminum (RAL) and SO[sub 4][sup *] was far more significant (r=0.93) compared with the corresponding correlations between RAL and TOC (r=0.40). The NC of TOC was found to be most affected by compounds in precipitation, primarily the inputs of sea salts. In the most acidified areas, the influence from strong acid inputs also affects the NC of TOC, but less significantly. Variations in sea salt inputs (primarily NaCl) are more important for the temporary variation in NC of TOC compared with H[sup +] ions at these sites. At a certain TOC level, the weak organic acids may affect the streamwater pH. A comparison between measured and calculated concentrations of organic Al indicated that the dissociation constants (pK-values) of the organic acids present at Birkenes must be higher and/or the Al-complexing constants lower compared with the constants given by the programme. 55 refs., 10 figs., 8 tabs.

OSTI ID:
6448476
Journal Information:
Environment International; (United States), Vol. 20:6; ISSN 0160-4120
Country of Publication:
United States
Language:
English