g factors and related magnetic properties of molecules. Formulation of theory and calculations for H/sub 2//sup ts+/, HD/sup +/, and D/sub 2//sup ts+/

Journal Article · Mon Jan 01 00:00:00 EST 1979 · Phys. Rev., A; (United States)

DOI:https://doi.org/10.1103/PhysRevA.19.17· OSTI ID:6446911

Hegstrom, R A

A theoretical framework is presented from which precise electronic g values for molecules may be calculated. The theory is applied to the calculation of g factors and related magnetic properties for H/sub 2//sup ts+/, HD/sup +/, and D/sub 2//sup ts+/. The average g value for the ground state of each of these molecular ions is predicted to be shifted by about 3 ppm from the g factor for atomic hydrogen. The results are expected to be accurate to about 0.1 ppm, and when compared with future experimental measurements may provide the first precise test of the theory of molecular g factors.

• Research Organization: Department of Chemistry, Wake Forest University, Winston-Salem, North Carolina 27109
• OSTI ID: 6446911
• Journal Information: Phys. Rev., A; (United States), Vol. 19:1
• Country of Publication: United States
• Language: English

Related Subjects

74 ATOMIC AND MOLECULAR PHYSICS
DEUTERIUM IONS
LANDE FACTOR
MOLECULAR IONS
HYDROGEN DEUTERIDE
HYDROGEN IONS 1 PLUS
MAGNETIC FIELDS
CATIONS
CHARGED PARTICLES
DEUTERIDES
DEUTERIUM COMPOUNDS
HYDROGEN COMPOUNDS
HYDROGEN IONS
IONS
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory