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Title: Participation of the anthracene/trans,trans-2,4-hexadiene exciplex in anthracene photodimerization

Abstract

Observations with the anthracene(A)/trans,trans-2,3-hexadiene(D) system revealing diene enhancement of the photodimerization in the parent hydrocarbon were previously reported. There was disagreement on the dimerization mechanism. Detailed observations are reported which firmly establishes a mechanism involving reaction of ground state anthracene with an exciplex /sup 1/(AD) as the mechanism for enhanced photodimerization in this system. (JSR)

Authors:
; ; ;
Publication Date:
Research Org.:
Florida State Univ., Tallahassee
OSTI Identifier:
6428731
Alternate Identifier(s):
OSTI ID: 6428731
Report Number(s):
CONF-790415-P1
Journal ID: CODEN: ACPCA
Resource Type:
Conference
Journal Name:
Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States)
Additional Journal Information:
Journal Volume: 24:1; Conference: 177. ACS national meeting, Honolulu, HI, USA, 1 Apr 1979
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ANTHRACENE; DIMERIZATION; PHOTOCHEMICAL REACTIONS; CHEMICAL REACTION KINETICS; DIENES; AROMATICS; CHEMICAL REACTIONS; CONDENSED AROMATICS; HYDROCARBONS; KINETICS; ORGANIC COMPOUNDS; POLYENES; POLYMERIZATION; REACTION KINETICS 400500* -- Photochemistry

Citation Formats

Saltiel, J., Townsend, D.E., Watson, B.D., and Shannon, P. Participation of the anthracene/trans,trans-2,4-hexadiene exciplex in anthracene photodimerization. United States: N. p., 1979. Web.
Saltiel, J., Townsend, D.E., Watson, B.D., & Shannon, P. Participation of the anthracene/trans,trans-2,4-hexadiene exciplex in anthracene photodimerization. United States.
Saltiel, J., Townsend, D.E., Watson, B.D., and Shannon, P. Thu . "Participation of the anthracene/trans,trans-2,4-hexadiene exciplex in anthracene photodimerization". United States.
@article{osti_6428731,
title = {Participation of the anthracene/trans,trans-2,4-hexadiene exciplex in anthracene photodimerization},
author = {Saltiel, J. and Townsend, D.E. and Watson, B.D. and Shannon, P.},
abstractNote = {Observations with the anthracene(A)/trans,trans-2,3-hexadiene(D) system revealing diene enhancement of the photodimerization in the parent hydrocarbon were previously reported. There was disagreement on the dimerization mechanism. Detailed observations are reported which firmly establishes a mechanism involving reaction of ground state anthracene with an exciplex /sup 1/(AD) as the mechanism for enhanced photodimerization in this system. (JSR)},
doi = {},
journal = {Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States)},
number = ,
volume = 24:1,
place = {United States},
year = {1979},
month = {2}
}

Conference:
Other availability
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