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Title: Magnetic field induced absorption of zero-phonon lines in (Ru(bpy)3)(PF6)2 and (Ru(bpy)3)(ClO4)2 single crystals

Abstract

In recent studies they have investigated the spectroscopic properties of (Ru(bpy)3)X2 single crystals (with X = PF6 and ClO4 and bpy = 2,2'-bipyridine). In particular, it was possible to discover sharp, purely electronic (zero-phonon) transitions corresponding to the two lowest excited states in the emission spectra of (Ru(bpy)3)(ClO4)2 and (Ru(bpy)3)(PF6)2. They communicate here the observation of the corresponding zero-phonon lines also in the absorption spectra and report on changes of the absorption under application of high magnetic fields.

Authors:
; ;
Publication Date:
Research Org.:
Universitaet Regensburg, West Germany
OSTI Identifier:
6425228
Resource Type:
Journal Article
Journal Name:
Inorg. Chem.; (United States)
Additional Journal Information:
Journal Volume: 26:11
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BIPYRIDINES; CRYSTAL STRUCTURE; MOLECULAR STRUCTURE; RUTHENIUM COMPLEXES; ABSORPTION SPECTROSCOPY; EXPERIMENTAL DATA; MAGNETIC FIELDS; PHONONS; AZINES; COMPLEXES; DATA; HETEROCYCLIC COMPOUNDS; INFORMATION; NUMERICAL DATA; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PYRIDINES; QUASI PARTICLES; SPECTROSCOPY; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties; 400500 - Photochemistry

Citation Formats

Hensler, G., Gallhuber, E., and Yersin, H. Magnetic field induced absorption of zero-phonon lines in (Ru(bpy)3)(PF6)2 and (Ru(bpy)3)(ClO4)2 single crystals. United States: N. p., 1987. Web. doi:10.1021/ic00258a001.
Hensler, G., Gallhuber, E., & Yersin, H. Magnetic field induced absorption of zero-phonon lines in (Ru(bpy)3)(PF6)2 and (Ru(bpy)3)(ClO4)2 single crystals. United States. doi:10.1021/ic00258a001.
Hensler, G., Gallhuber, E., and Yersin, H. Wed . "Magnetic field induced absorption of zero-phonon lines in (Ru(bpy)3)(PF6)2 and (Ru(bpy)3)(ClO4)2 single crystals". United States. doi:10.1021/ic00258a001.
@article{osti_6425228,
title = {Magnetic field induced absorption of zero-phonon lines in (Ru(bpy)3)(PF6)2 and (Ru(bpy)3)(ClO4)2 single crystals},
author = {Hensler, G. and Gallhuber, E. and Yersin, H.},
abstractNote = {In recent studies they have investigated the spectroscopic properties of (Ru(bpy)3)X2 single crystals (with X = PF6 and ClO4 and bpy = 2,2'-bipyridine). In particular, it was possible to discover sharp, purely electronic (zero-phonon) transitions corresponding to the two lowest excited states in the emission spectra of (Ru(bpy)3)(ClO4)2 and (Ru(bpy)3)(PF6)2. They communicate here the observation of the corresponding zero-phonon lines also in the absorption spectra and report on changes of the absorption under application of high magnetic fields.},
doi = {10.1021/ic00258a001},
journal = {Inorg. Chem.; (United States)},
number = ,
volume = 26:11,
place = {United States},
year = {1987},
month = {6}
}