Transformed steroids. Communication 154. Production of a 17-spirooxetan-20-one under conditions of 21-hydroxylation of 16. cap alpha. -acetamidopregn-5-ene-3. beta. ,17. cap alpha. -diol-20-one with iodosobenzene diacetate
Journal Article
·
· Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States)
OSTI ID:6417831
The possibility of the one-step synthesis of 17-spirooxetan-20-ones from 17..beta..-acetyl-17..cap alpha..-hydroxy steroids with the aid of iodosobenzene diacetate in a methanol solution of alkali was demonstrated.
- Research Organization:
- N.D. Zelinskii Institute of Organic Chemistry, Moscow, USSR
- OSTI ID:
- 6417831
- Journal Information:
- Bull. Acad. Sci. USSR, Div. Chem. Sci. (Engl. Transl.); (United States), Vol. 35:7; Other Information: Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya; 35: No.7, 1659-1663(Jul 1986)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
CATALYTIC EFFECTS
HETEROCYCLIC OXYGEN COMPOUNDS
SYNTHESIS
IODINATED AROMATIC HYDROCARBONS
KETONES
HYDROXYLATION
STEROIDS
ELECTRON SPIN RESONANCE
INFRARED SPECTRA
MASS SPECTRA
METHANOL
STRUCTURAL CHEMICAL ANALYSIS
ALCOHOLS
AROMATICS
CARBOXYLIC ACID SALTS
HALOGENATED AROMATIC HYDROCARBONS
HYDROXY COMPOUNDS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
RESONANCE
SPECTRA
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ACETATES
CATALYTIC EFFECTS
HETEROCYCLIC OXYGEN COMPOUNDS
SYNTHESIS
IODINATED AROMATIC HYDROCARBONS
KETONES
HYDROXYLATION
STEROIDS
ELECTRON SPIN RESONANCE
INFRARED SPECTRA
MASS SPECTRA
METHANOL
STRUCTURAL CHEMICAL ANALYSIS
ALCOHOLS
AROMATICS
CARBOXYLIC ACID SALTS
HALOGENATED AROMATIC HYDROCARBONS
HYDROXY COMPOUNDS
MAGNETIC RESONANCE
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
ORGANIC IODINE COMPOUNDS
ORGANIC OXYGEN COMPOUNDS
RESONANCE
SPECTRA
400201* - Chemical & Physicochemical Properties