Identification of CW two-photon transitions in Na/sub 2/ and NaK
This thesis reports on the two-photon visible excitation spectra of sodium and potassium vapors. In the past, similar work has been performed on sodium and many atomic two-photon transitions have been characterized. However, many extra signals exist which do not possess the ground, 3S, state hyperfine splitting. These extra transitions are due to the sodium dimer Na/sub 2/. 79 such transitions, from 5800A - 6500A, which lie within the resolution of the apparatus have been studied. The molecules are excited with a lowpower narrow band counterpropagating cw dye laser beam and two-photon fluorescence. The fluorescence intensities of many of these transitions are greater than the 3S to 5S and 3S to 4D atomic signals, where the 3P enhancing state lies 300 cm/sup -1/ from resonance. By comparing the number density of the atomic with any molecular ground state and also the two-photon transition rates to excited states, the intermediate enhancing state for a two-photon transition in Na/sub 2/ can be predicted to be less than 1 cm/sup -1/ from resonance with the two-photon transition. This observation, along with published Dunham coefficients, is used to identify the states involved in the two-photon transitions.
- Research Organization:
- Stanford Univ., CA (USA)
- OSTI ID:
- 6408284
- Resource Relation:
- Other Information: Thesis (Ph. D.)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
POTASSIUM COMPLEXES
VISIBLE SPECTRA
SODIUM
SODIUM COMPLEXES
DIMERS
ENERGY-LEVEL TRANSITIONS
EXCITED STATES
EXPERIMENTAL DATA
FLUORESCENCE
VAPORS
ALKALI METAL COMPLEXES
ALKALI METALS
COMPLEXES
DATA
ELEMENTS
ENERGY LEVELS
FLUIDS
GASES
INFORMATION
LUMINESCENCE
METALS
NUMERICAL DATA
SPECTRA
640302* - Atomic
Molecular & Chemical Physics- Atomic & Molecular Properties & Theory
400201 - Chemical & Physicochemical Properties