Phase equilibria of the ternary system: uranium hexafluoride-chlorine trifluoride-hydrogen fluoride. Part V. Liquid-vapor equilibria of the binary system: chlorine trifluoride-hydrogen fluoride

Technical Report · Fri Feb 26 00:00:00 EST 1954

OSTI ID:6405088

McGill, R M; Barber, E J

The liquid-vapor equilibrium of the binary system chlorine trifluoride-hydrogen fluoride has been investigated at total pressures of 1.5, 2.0, 2.5, 3.0, and 4.0 atmospheres absolute by means of a nickel Othmer-type equilibrium still. The system is azeotropic at all these pressures, the minimum boiling azeotrope mixture containing about 67 formula per cent chlorine trifluoride. The possibility that the azeotrope is a molecular compound is considered. Activity coefficients for the components in solution are calculated from the equilibria data. 11 refs., 6 figs., 3 tabs.

• Research Organization: Carbide and Carbon Chemicals Corp., Oak Ridge, TN (USA)
• DOE Contract Number: AC05-84OT21400
• OSTI ID: 6405088
• Report Number(s): DOE/OT/21400-T12; K-1103; ON: DE86003585
• Resource Relation: Other Information: Declassified 24 Feb 1972
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CHLORINE FLUORIDES
EQUILIBRIUM
PHASE DIAGRAMS
REACTION KINETICS
THERMODYNAMIC ACTIVITY
HYDROFLUORIC ACID
AZEOTROPE
BINARY MIXTURES
CHEMICAL COMPOSITION
EXPERIMENTAL DATA
GASES
LIQUIDS
MEDIUM PRESSURE
PRESSURE DEPENDENCE
TEMPERATURE DEPENDENCE
CHLORINE COMPOUNDS
DATA
DIAGRAMS
DISPERSIONS
FLUIDS
FLUORIDES
FLUORINE COMPOUNDS
HALIDES
HALOGEN COMPOUNDS
HYDROGEN COMPOUNDS
INFORMATION
INORGANIC ACIDS
KINETICS
MIXTURES
NUMERICAL DATA
400201* - Chemical & Physicochemical Properties