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Title: Synthesis and reactivity of propionyliridium complexes. Competitive reductive elimination of C-H and H-H bonds from a propionyldihydridoiridium complex

Journal Article · · Organometallics; (USA)
DOI:https://doi.org/10.1021/om00117a029· OSTI ID:6380270
;  [1]
  1. Univ. of Rochester, NY (USA)
+ Show Author Affiliations

The complex Ir({eta}{sup 2}-C{sub 2}H{sub 4})(Et)(CO)(dppe) reacts with CO to produce initially Ir(Et)(CO){sub 2}(dppe), which then undergoes subsequent CO insertion and carbonylation to form Ir(C(O)Et)(CO){sub 2}(dppe). This latter complex was isolated and structurally characterized: space group P{bar 1} (no. 2), a = 11.046 (2) {angstrom}, b = 16.596 (4) {angstrom}, c = 8.523 (2) {angstrom}, {alpha} = 93.93 (2){degree}, {beta} = 110.94 (2){degree}, {gamma} = 95.24 (2){degree}, V = 1444 (1) {angstrom}{sup 3}, Z = 2. The complex Ir(C(O)Et)(CO){sub 2}(dppe) possesses a distorted trigonal-biyramidal geometry with the propionyl group in an axial position, the dppe ligand spanning the other axial and an equatorial position, and two equatorially disposed carbonyl groups.

OSTI ID:
6380270
Journal Information:
Organometallics; (USA), Vol. 9:3; ISSN 0276-7333
Country of Publication:
United States
Language:
English

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Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
IRIDIUM COMPLEXES
CRYSTAL STRUCTURE
REACTIVITY
SYNTHESIS
DATA ANALYSIS
EXPERIMENTAL DATA
MEASURING INSTRUMENTS
MEASURING METHODS
ORGANOMETALLIC COMPOUNDS
COMPLEXES
DATA
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties