Crystal and molecular structure of aquo(dihydrogen ethylenediamine-di(isopropylphosphonato) copper(II) monohydrate (Cu(H/sub 2/EDDIPH)H/sub 2/O) x H/sub 2/O
An x-ray structural investigation of (Cu(H/sub 2/EDDIPH)H/sub 2/O) x H/sub 2/O, where H/sub 2/EDDIPH/sup 2 -/ denotes an acidic ethylenediaminedi(isopropylphosphonate) anion, has been carried out (lambda Mo K..cap alpha.., 1506 reflections, direct method, anisotropic least-squares method to R = 0.036). The crystals are orthorhombic: a = 6.685(1), b = 15.605(4), c = 15.159(4) A, Z = 4, space group Pbc2/sub 1/. The Cu atom has tetragonal-pyramidal coordination with two O atoms and two N atoms of the tetradentate ligand in the base and with the O atom of a water molecule at the apex. The bond lengths in the polyhedron are as follows: Cu-O = 1.912(5) and 1.968(5) A, Cu-O/sub w1/ = 2.302(5), and Cu-N = 2.014(6) and 2.059(6) A. The molecules exist in a meso form. Each of the two terminal ionized oxygen atoms of the monoprotonated phosphonate groups serves as an acceptor in three H bonds of the O...H-O, O...H-N, and O...H/sub w1/-O/sub w1/ types (w1 denotes a coordinated water molecule) with an adjacent molecule, one of the H bonds being weakened. Two H rings are formed as a result. One is six-membered and is similar to the ring discovered in the structure of ethylenediaminetetramethylphosphonic acid. A comparison with the structure of the complex compound of H/sub 4/EDDIPH with oxonium cations has been made.
- Research Organization:
- All-Union Scientific-Research Institute of Chemical Reagents and Ultrapure Chemical Substances, USSR
- OSTI ID:
- 6367544
- Journal Information:
- Sov. J. Coordinat. Chem.; (United States), Vol. 12:7; Other Information: Translated from Koordinatsionnaya Khimiya; 12: No.7, 981-990(Jul 1986)
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and structure of heptaaqua(nitrilotris(methylenephosphonato))(dibarium)sodium monohydrate [Na(H{sub 2}O){sub 3}(μ{sup 6}-NH(CH{sub 2}PO{sub 3}){sub 3})(μ-H{sub 2}O){sub 3}Ba{sub 2}(H{sub 2}O)] · H{sub 2}O
Crystal and molecular structure of four copper(II) ethylenediaminedisuccinates, [Cu{sub 2}(RR,SS-Edds)] . 6H{sub 2}O, Ba{sub 2}[Cu(RR,SS-Edds)](ClO{sub 4}){sub 2} . 8H{sub 2}O, Ba[Cu(SS-HEdds)]ClO{sub 4} . 2H{sub 2}O, and Ba{sub 3}[Cu{sub 2}(RR,SS-Edds){sub 2}](ClO{sub 4}){sub 2} . 6H{sub 2}O
Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
COPPER COMPLEXES
MOLECULAR STRUCTURE
ORTHORHOMBIC LATTICES
PHOSPHONATES
COMPLEXOMETRY
AMINES
BINDING ENERGY
BOND ANGLE
BOND LENGTHS
CATALYSTS
CATALYTIC EFFECTS
CHELATING AGENTS
CHEMICAL BONDS
COORDINATION VALENCES
ELECTRONS
HYDROGEN
LATTICE PARAMETERS
SPACE GROUPS
STRUCTURAL CHEMICAL ANALYSIS
COMPLEXES
CRYSTAL LATTICES
CRYSTAL STRUCTURE
DIMENSIONS
ELEMENTARY PARTICLES
ELEMENTS
ENERGY
FERMIONS
LENGTH
LEPTONS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
TRANSITION ELEMENT COMPLEXES
VALENCE
400201* - Chemical & Physicochemical Properties
360602 - Other Materials- Structure & Phase Studies