Structural consequences of oxidation in photosynthetic models. Crystal structure of (perchlorato)-(5,10,15,20-tetraphenylporphinato)magnesium(II)
Journal Article
·
· Inorg. Chem.; (United States)
- Brookhaven National Lab., Upton, NY
This report is an X-ray determination of a magnesium porphyrin radical, (perchlorato)(5,10,15,20-tetraphenylporphinato)magnesium(II), MgTPP/sup +/.ClO/sub 4//sup -5/ as a model of the structural and stereochemical consequences of the loss of an electron in photosynthetic chromophores.
- DOE Contract Number:
- AC02-76CH00016
- OSTI ID:
- 6347900
- Journal Information:
- Inorg. Chem.; (United States), Vol. 22:2
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MAGNESIUM COMPLEXES
CRYSTAL STRUCTURE
BOND LENGTHS
CRYSTALLOGRAPHY
ORGANIC CHLORINE COMPOUNDS
OXIDATION
PARAMETRIC ANALYSIS
ALKALINE EARTH METAL COMPLEXES
CHEMICAL REACTIONS
COMPLEXES
DIMENSIONS
LENGTH
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
MAGNESIUM COMPLEXES
CRYSTAL STRUCTURE
BOND LENGTHS
CRYSTALLOGRAPHY
ORGANIC CHLORINE COMPOUNDS
OXIDATION
PARAMETRIC ANALYSIS
ALKALINE EARTH METAL COMPLEXES
CHEMICAL REACTIONS
COMPLEXES
DIMENSIONS
LENGTH
ORGANIC COMPOUNDS
ORGANIC HALOGEN COMPOUNDS
400201* - Chemical & Physicochemical Properties