skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Dielectrics for GaN based MIS-diodes

Abstract

GaN MIS diodes were demonstrated utilizing AlN and Ga{sub 2}O{sub 3}(Gd{sub 2}O{sub 3}) as insulators. A 345 {angstrom} of AlN was grown on the MOCVD grown n-GaN in a MOMBE system using trimethylamine alane as Al precursor and nitrogen generated from a wavemat ECR N2 plasma. For the Ga{sub 2}O{sub 3}(Gd{sub 2}O{sub 3}) growth, a multi MBE chamber was used and a 195 {angstrom} oxide is E-beam evaporated from a single crystal source of Ga{sub 5}Gd{sub 3}O{sub 12}. The forward breakdown voltage of AlN and Ga{sub 2}O{sub 3}(Gd{sub 2}O{sub 3}) diodes are 5V and 6V, respectively, which are significantly improved from {approximately} 1.2 V of schottky contact. From the C-V measurements, both kinds of diodes showed good charge modulation from accumulation to depletion at different frequencies. The insulator GaN interface roughness and the thickness of the insulator were measured with x-ray reflectivity.

Authors:
; ;  [1]
  1. Univ. of Florida, Gainesville, FL (United States) [and others
Publication Date:
Research Org.:
Sandia National Labs., Albuquerque, NM (United States)
Sponsoring Org.:
USDOE Office of Financial Management and Controller, Washington, DC (United States); National Science Foundation, Washington, DC (United States); Office of Naval Research, Washington, DC (United States); Defense Advanced Research Projects Agency, Arlington, VA (United States); Electric Power Research Inst., Palo Alto, CA (United States)
OSTI Identifier:
634115
Report Number(s):
SAND-98-0524C; CONF-971201-
ON: DE98004137; BR: YN0100000; CNN: Grant ECS-9522887; TRN: AHC2DT01%%126
DOE Contract Number:
AC04-94AL85000
Resource Type:
Technical Report
Resource Relation:
Conference: 1997 fall meeting of the Materials Research Society, Boston, MA (United States), 1-5 Dec 1997; Other Information: PBD: Feb 1998
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING NOT INCLUDED IN OTHER CATEGORIES; SEMICONDUCTOR DIODES; GALLIUM NITRIDES; ALUMINIUM NITRIDES; CHEMICAL VAPOR DEPOSITION; MOLECULAR BEAM EPITAXY; ELECTRICAL PROPERTIES; GALLIUM OXIDES; GADOLINIUM OXIDES; EXPERIMENTAL DATA

Citation Formats

Ren, F., Abernathy, C.R., and MacKenzie, J.D.. Dielectrics for GaN based MIS-diodes. United States: N. p., 1998. Web. doi:10.2172/634115.
Ren, F., Abernathy, C.R., & MacKenzie, J.D.. Dielectrics for GaN based MIS-diodes. United States. doi:10.2172/634115.
Ren, F., Abernathy, C.R., and MacKenzie, J.D.. Sun . "Dielectrics for GaN based MIS-diodes". United States. doi:10.2172/634115. https://www.osti.gov/servlets/purl/634115.
@article{osti_634115,
title = {Dielectrics for GaN based MIS-diodes},
author = {Ren, F. and Abernathy, C.R. and MacKenzie, J.D.},
abstractNote = {GaN MIS diodes were demonstrated utilizing AlN and Ga{sub 2}O{sub 3}(Gd{sub 2}O{sub 3}) as insulators. A 345 {angstrom} of AlN was grown on the MOCVD grown n-GaN in a MOMBE system using trimethylamine alane as Al precursor and nitrogen generated from a wavemat ECR N2 plasma. For the Ga{sub 2}O{sub 3}(Gd{sub 2}O{sub 3}) growth, a multi MBE chamber was used and a 195 {angstrom} oxide is E-beam evaporated from a single crystal source of Ga{sub 5}Gd{sub 3}O{sub 12}. The forward breakdown voltage of AlN and Ga{sub 2}O{sub 3}(Gd{sub 2}O{sub 3}) diodes are 5V and 6V, respectively, which are significantly improved from {approximately} 1.2 V of schottky contact. From the C-V measurements, both kinds of diodes showed good charge modulation from accumulation to depletion at different frequencies. The insulator GaN interface roughness and the thickness of the insulator were measured with x-ray reflectivity.},
doi = {10.2172/634115},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Sun Feb 01 00:00:00 EST 1998},
month = {Sun Feb 01 00:00:00 EST 1998}
}

Technical Report:

Save / Share:
  • Abstract not provided.
  • GaN is a crucial material for light-emitting diodes (LEDs) emitting in the violet-to-green range. Despite its good performance, it still suffers from significant technical limitations. In particular, the efficiency of GaN-based LEDs decreases at high current (“current droop”) and high temperature (“temperature droop”). This is problematic in some lighting applications, where a high-power operation is required. This program studied the use of particular substrates to improve the efficiency of GaN-based LEDs: bulk semipolar (SP) GaN substrates. These substrates possess a very high material quality, and physical properties which are distinctly different from legacy substrates currently used in the LED industry.more » The program focused on the development of accurate metrology to quantify the performance of GaN-based LEDs, and on improvement to LED quality and design on SP substrates. Through a thorough optimization process, we demonstrated violet LEDs with very high internal quantum efficiency, exceeding 85% at high temperature and high current. We also investigated longer-wavelength blue emitters, but found that the limited strain budget was a key limitation.« less
  • The purpose of this laboratory-directed research and development (LDRD) project was to develop and assess novel low-permittivity dielectric materials for applications as interlevel dielectrics (ILDs) in Si-based microelectronics. There were three classes of materials investigated: (1) novel covalently-bonded ceramics containing carbon, boron, and/or nitrogen, (2) fluorinated SiO{sub 2} (SiOF), and (3) plasma polymerized fluorocarbon (PPFC). The specific advantages and disadvantages for each potential low k ILD material were evaluated. It was discovered that highly energetic deposition processes are required for the formation of thermally and environmentally stable carbon or boron nitride ceramics, and the resulting films may have many potentiallymore » valuable applications, such as diffusion barriers, tribological coatings, micro-sensor materials, etc. The films are not suitable as low k ILDs, however, because the highly energetic deposition process leads to films with high atomic density, and this leads to high dielectric constants. SiOF shows a promise as low k ILD material for near-term applications, but special passivation or encapsulation strategies may be required in order to reduce two instability problems that the authors have discovered: moisture absorption and thermal instability of the SiOF/Al interface. PPFC films offer promise for even lower dielectric constant ILDs than SiOF, but it will be necessary to develop new strategies to passivate the free radicals in the films generated during deposition. These free radicals lead to increase in dielectric loss over time when the films are exposed to room ambient conditions.« less
  • The temperature dependence of the electrical conductivity and thermal decomposition characteristics of several phenolic- and silicone-based materials of interest for fireset case housings have been measured to 600 to 700/sup 0/C. The materials are phenolic or silicone resins reinforced with glass chopped fabric or cloth. The conductivity temperature dependence was measured during decomposition in a nitrogen atmosphere at a heating rate of approx. 10/sup 0/C/minute. Applied electric fields were from 4 x 10/sup 2/ to 4 x 10/sup 3/ volts/cm. Thermal decomposition characteristics were investigated by mass spectroscopy in vacuum and thermal gravimetric analysis in nitrogen and air. Nearly ohmicmore » voltage-current characteristics were obtained, except where decomposition and/or outgassing was pronounced.« less