Molecular orbitual studies of the bonding in heavy element organometallics: Progress report
Technical Report
·
OSTI ID:6335310
Progress to date is described in 2 major areas: (1) Tris(cyclopentadienyl) actinide complexes. We have made considerable progress in our studies of the electronic structure of organoactinide compounds containing three cyclopentadienyl ligands: investigations of the ''base-free'' compounds Cp/sub 3/An, and investigations of the interaction of Cp/sub 3/An compounds with a fourth ligand, L. (2) Actinide-containing molecules with metal-metal bonds, actinide-actinide bonds, and actinide-transition metal bonds.
- Research Organization:
- Ohio State Univ. Research Foundation, Columbus (USA)
- DOE Contract Number:
- FG02-86ER13529
- OSTI ID:
- 6335310
- Report Number(s):
- DOE/ER/13529-1; ON: DE89011589
- Resource Relation:
- Other Information: Portions of this document are illegible in microfiche products
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
ACTINIDE COMPLEXES
ELECTRONIC STRUCTURE
CHEMICAL BONDS
CYCLOPENTADIENE
LIGANDS
METALS
MOLECULAR ORBITAL METHOD
MOLECULES
ORGANOMETALLIC COMPOUNDS
PROGRESS REPORT
TRANSITION ELEMENTS
ALKENES
COMPLEXES
CYCLOALKENES
DIENES
DOCUMENT TYPES
ELEMENTS
HYDROCARBONS
ORGANIC COMPOUNDS
POLYENES
400201* - Chemical & Physicochemical Properties
400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
ACTINIDE COMPLEXES
ELECTRONIC STRUCTURE
CHEMICAL BONDS
CYCLOPENTADIENE
LIGANDS
METALS
MOLECULAR ORBITAL METHOD
MOLECULES
ORGANOMETALLIC COMPOUNDS
PROGRESS REPORT
TRANSITION ELEMENTS
ALKENES
COMPLEXES
CYCLOALKENES
DIENES
DOCUMENT TYPES
ELEMENTS
HYDROCARBONS
ORGANIC COMPOUNDS
POLYENES
400201* - Chemical & Physicochemical Properties
400702 - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials