skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Entropy of a nonequilibrium system

Abstract

Three definitions of entropy for a nonequilibrium system of particles, driven homogeneously by external forces and thermostatted homogeneously by a feedback mechanism, are discussed. The first is proposed to be S(t) = -k, i.e., the nonequilibrium ensemble average of the logarithm of the thermostatted equilibrium distribution function f/sub xi/. We show here, for a specific example, namely, the Nose-Hoover thermostat, that the entropy so defined reduces properly to the equilibrium result when the external forces are turned off, that this entropy behaves correctly when the thermostat is turned off, and that the thermostatted steady state is achievable. A reasonable alternative definition from information theory, namely replacing f/sub xi/ by the nonequilibrium distribution function f, is shown to give incorrect results. If, however, the distribution function f is coarse grained in time to give f-bar, then the resulting coarse-grained information-theory entropy, like the first definition, satisfies the requirements of the nonequilibrium entropy, with the added advantage of being easier to interpret in terms of the number of accessible states. Additional implications are discussed.

Authors:
Publication Date:
Research Org.:
Los Alamos National Laboratory, Los Alamos, New Mexico 87545
OSTI Identifier:
6324710
Resource Type:
Journal Article
Journal Name:
Phys. Rev. A; (United States)
Additional Journal Information:
Journal Volume: 33:2
Country of Publication:
United States
Language:
English
Subject:
71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; ENTROPY; DISTRIBUTION FUNCTIONS; EQUILIBRIUM; THERMODYNAMICS; FUNCTIONS; PHYSICAL PROPERTIES; THERMODYNAMIC PROPERTIES; 657006* - Theoretical Physics- Statistical Physics & Thermodynamics- (-1987)

Citation Formats

Holian, B L. Entropy of a nonequilibrium system. United States: N. p., 1986. Web. doi:10.1103/PhysRevA.33.1152.
Holian, B L. Entropy of a nonequilibrium system. United States. https://doi.org/10.1103/PhysRevA.33.1152
Holian, B L. Sat . "Entropy of a nonequilibrium system". United States. https://doi.org/10.1103/PhysRevA.33.1152.
@article{osti_6324710,
title = {Entropy of a nonequilibrium system},
author = {Holian, B L},
abstractNote = {Three definitions of entropy for a nonequilibrium system of particles, driven homogeneously by external forces and thermostatted homogeneously by a feedback mechanism, are discussed. The first is proposed to be S(t) = -k, i.e., the nonequilibrium ensemble average of the logarithm of the thermostatted equilibrium distribution function f/sub xi/. We show here, for a specific example, namely, the Nose-Hoover thermostat, that the entropy so defined reduces properly to the equilibrium result when the external forces are turned off, that this entropy behaves correctly when the thermostat is turned off, and that the thermostatted steady state is achievable. A reasonable alternative definition from information theory, namely replacing f/sub xi/ by the nonequilibrium distribution function f, is shown to give incorrect results. If, however, the distribution function f is coarse grained in time to give f-bar, then the resulting coarse-grained information-theory entropy, like the first definition, satisfies the requirements of the nonequilibrium entropy, with the added advantage of being easier to interpret in terms of the number of accessible states. Additional implications are discussed.},
doi = {10.1103/PhysRevA.33.1152},
url = {https://www.osti.gov/biblio/6324710}, journal = {Phys. Rev. A; (United States)},
number = ,
volume = 33:2,
place = {United States},
year = {1986},
month = {2}
}