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Title: Solubilities for the two ternary systems water + lithium bromide + lithium iodide and water + lithium chloride + lithium nitrate at various temperatures

Abstract

The analyses of absorption refrigeration and heat pump systems need extensive thermodynamic information such as heat capacities, heats of mixing, vapor pressures, solubilities, densities, viscosities, and surface tensions for working medium plus absorbent systems. Solubilities for the water + lithium bromide + lithium iodide (salt mole ratio 4:1) and the water + lithium chloride + lithium nitrate (salt model ratio 2.8:1) systems were measured by means of visual polythermal method from 277.75 to 415.15 K and from 284.85 to 351.75 K, respectively. The transition point for the water + lithium bromide + lithium iodide system existed at 65.3 mass % salts and 293.85 K and at 54.2 mass % salts and 295.75 K for the water + lithium chloride + lithium nitrate system. Two solid-liquid phases for these two ternary systems were stable below and above the individual transition point. Two least-squares regression equations as a function of absolute temperatures were obtained from the individual measured solubility data for these two ternary systems. The maximum and average absolute deviations of the calculated values from the individual experimental data were 0.29 and 0.10 % for the water + lithium chloride + lithium nitrate system, respectively.

Authors:
; ; ;  [1]
  1. Kansai Univ., Osaka (Japan). Dept. of Chemical Engineering
Publication Date:
OSTI Identifier:
6298143
Resource Type:
Journal Article
Journal Name:
Journal of Chemical and Engineering Data; (United States)
Additional Journal Information:
Journal Volume: 38:3; Journal ID: ISSN 0021-9568
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; ABSORPTION REFRIGERATION CYCLE; WORKING FLUIDS; LITHIUM BROMIDES; SOLUBILITY; LITHIUM IODIDES; LITHIUM NITRATES; AQUEOUS SOLUTIONS; EXPERIMENTAL DATA; PHASE STUDIES; REGRESSION ANALYSIS; TEMPERATURE RANGE 0273-0400 K; ALKALI METAL COMPOUNDS; BROMIDES; BROMINE COMPOUNDS; DATA; DISPERSIONS; FLUIDS; HALIDES; HALOGEN COMPOUNDS; INFORMATION; INORGANIC PHOSPHORS; IODIDES; IODINE COMPOUNDS; LITHIUM COMPOUNDS; LITHIUM HALIDES; MATHEMATICS; MIXTURES; NITRATES; NITROGEN COMPOUNDS; NUMERICAL DATA; OXYGEN COMPOUNDS; PHOSPHORS; SOLUTIONS; STATISTICS; TEMPERATURE RANGE; 400201* - Chemical & Physicochemical Properties; 320106 - Energy Conservation, Consumption, & Utilization- Building Equipment- (1987-)

Citation Formats

Iyoki, Shigeki, Iwasaki, Shozo, Kuriyama, Yutaka, and Uemura, Tadashi. Solubilities for the two ternary systems water + lithium bromide + lithium iodide and water + lithium chloride + lithium nitrate at various temperatures. United States: N. p., 1993. Web. doi:10.1021/je00011a016.
Iyoki, Shigeki, Iwasaki, Shozo, Kuriyama, Yutaka, & Uemura, Tadashi. Solubilities for the two ternary systems water + lithium bromide + lithium iodide and water + lithium chloride + lithium nitrate at various temperatures. United States. https://doi.org/10.1021/je00011a016
Iyoki, Shigeki, Iwasaki, Shozo, Kuriyama, Yutaka, and Uemura, Tadashi. 1993. "Solubilities for the two ternary systems water + lithium bromide + lithium iodide and water + lithium chloride + lithium nitrate at various temperatures". United States. https://doi.org/10.1021/je00011a016.
@article{osti_6298143,
title = {Solubilities for the two ternary systems water + lithium bromide + lithium iodide and water + lithium chloride + lithium nitrate at various temperatures},
author = {Iyoki, Shigeki and Iwasaki, Shozo and Kuriyama, Yutaka and Uemura, Tadashi},
abstractNote = {The analyses of absorption refrigeration and heat pump systems need extensive thermodynamic information such as heat capacities, heats of mixing, vapor pressures, solubilities, densities, viscosities, and surface tensions for working medium plus absorbent systems. Solubilities for the water + lithium bromide + lithium iodide (salt mole ratio 4:1) and the water + lithium chloride + lithium nitrate (salt model ratio 2.8:1) systems were measured by means of visual polythermal method from 277.75 to 415.15 K and from 284.85 to 351.75 K, respectively. The transition point for the water + lithium bromide + lithium iodide system existed at 65.3 mass % salts and 293.85 K and at 54.2 mass % salts and 295.75 K for the water + lithium chloride + lithium nitrate system. Two solid-liquid phases for these two ternary systems were stable below and above the individual transition point. Two least-squares regression equations as a function of absolute temperatures were obtained from the individual measured solubility data for these two ternary systems. The maximum and average absolute deviations of the calculated values from the individual experimental data were 0.29 and 0.10 % for the water + lithium chloride + lithium nitrate system, respectively.},
doi = {10.1021/je00011a016},
url = {https://www.osti.gov/biblio/6298143}, journal = {Journal of Chemical and Engineering Data; (United States)},
issn = {0021-9568},
number = ,
volume = 38:3,
place = {United States},
year = {1993},
month = {7}
}