Reactivity of Y[sub 3](OR)[sub 7]Cl[sub 2](THF)[sub 2] with organoaluminum reagents. Formation of the yttrium-aluminum complexes Y(OR)[sub 3](AlMe[sub 3])[sub 3], Y(OR)[sub 3](AlMe[sub 3])[sub 2](THF), and Y(OR)[sub 3](AlMe[sub 2])Cl(THF)[sub 2] and the halides YCl[sub 3](DME)[sub 2] and YCl[sub 3](THF)[sub 3]Y[sub 3](OR)[sub 7]O (R = CMe[sub 3])

Evans, W J; Boyle, T J; Ziller, J W

doi:10.1021/ja00065a020

Title: Reactivity of Y[sub 3](OR)[sub 7]Cl[sub 2](THF)[sub 2] with organoaluminum reagents. Formation of the yttrium-aluminum complexes Y(OR)[sub 3](AlMe[sub 3])[sub 3], Y(OR)[sub 3](AlMe[sub 3])[sub 2](THF), and Y(OR)[sub 3](AlMe[sub 2])Cl(THF)[sub 2] and the halides YCl[sub 3](DME)[sub 2] and YCl[sub 3](THF)[sub 3]Y[sub 3](OR)[sub 7]O (R = CMe[sub 3])

Journal Article · Wed Jun 16 00:00:00 EDT 1993 · Journal of the American Chemical Society; (United States)

DOI:https://doi.org/10.1021/ja00065a020· OSTI ID:6297556

Evans, W J; Boyle, T J; Ziller, J W ^[1]

Univ. of California, Irvine (United States)

The trimetallic structure of Y[sub 3](OCMe[sub 3])[sub 7]Cl[sub 2](THF)[sub 2] (1), which is typically retained in reactions of yttrium tert-butoxide complexes, was easily disrupted by trimethylaluminum to generate a series of mixed-metal yttrium-aluminum compounds. 56 refs., 5 figs., 5 tabs.

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OSTI ID:: 6297556

Journal Information:: Journal of the American Chemical Society; (United States), Vol. 115:12; ISSN 0002-7863

Country of Publication:: United States

Language:: English

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37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALUMINIUM COMPLEXES
CRYSTAL STRUCTURE
SYNTHESIS
YTTRIUM COMPLEXES
EXPERIMENTAL DATA
LIGANDS
NUCLEAR MAGNETIC RESONANCE
ORGANOMETALLIC COMPOUNDS
X-RAY DIFFRACTION
COHERENT SCATTERING
COMPLEXES
DATA
DIFFRACTION
INFORMATION
MAGNETIC RESONANCE
NUMERICAL DATA
ORGANIC COMPOUNDS
RESONANCE
SCATTERING
TRANSITION ELEMENT COMPLEXES
400201* - Chemical & Physicochemical Properties
400102 - Chemical & Spectral Procedures

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