Thermochemistry of solutions of potassium alkyl xanthogenates and rubeanic acid with nitrobenzene and other nitrogen-containing compounds

Journal Article · Wed Jul 20 00:00:00 EDT 1988 · J. Appl. Chem. USSR (Engl. Transl.); (United States)

OSTI ID:6288260

Gorbatov, V V; Bordzilovskii, V Ya; Gerega, V F; Borovoi, A A; Dergunov, Yu I

The ability of rubeanic acid and potassium alkyl xanthogenates to form complexes with one another and also with nitrobenzene and other nitrogen-containing compounds was shown calorimetrically. The composition of these complexes was determined, and the stability constants and enthalpies of formation of the complexes were calculated. It was found that the formation of the potassium alkyl xanthogenate-nitrogen-containing compound complex is dependent on the natures of both the xanthogenate and the nitrogen-containing additive; the strength of the complex increases regularly with increase in the basicity of the nitrogen-containing compound.

• OSTI ID: 6288260
• Journal Information: J. Appl. Chem. USSR (Engl. Transl.); (United States), Vol. 61:2; Other Information: Translated from Zh. Prikl. Khim.; 61: No. 2, 327-331(Feb 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
AMIDES
PYROLYSIS
NITROBENZENE
ACTIVATION ENERGY
ORGANIC SULFUR COMPOUNDS
POTASSIUM COMPOUNDS
AROMATICS
BUTANOLS
CALORIMETRY
CARBONYLATION
CATALYSTS
CATALYTIC EFFECTS
CHEMICAL COMPOSITION
COMPLEXOMETRY
FORMATION HEAT
MIXING HEAT
ORGANIC NITROGEN COMPOUNDS
STABILITY
ALCOHOLS
ALKALI METAL COMPOUNDS
CHEMICAL REACTIONS
DECOMPOSITION
ENERGY
ENTHALPY
HYDROXY COMPOUNDS
NITRO COMPOUNDS
ORGANIC COMPOUNDS
PHYSICAL PROPERTIES
REACTION HEAT
THERMOCHEMICAL PROCESSES
THERMODYNAMIC PROPERTIES
400800* - Combustion
Pyrolysis
& High-Temperature Chemistry
400201 - Chemical & Physicochemical Properties