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Title: Spinel, YbFe2O4, and Yb2Fe3O7 types of structure for compounds in the In2O3 and Sc2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, Cu, or Zn) at temperatures over 1000C

Abstract

In the Sc2O3-Ga2O3-CuO, Sc2O3-Ga2O3-ZnO, and Sc2O3-Al2O3-CuO systems, ScGaCuO4, ScGaZnO4, and ScAlCuO4 with the YbFe2O4-type structure and Sc2Ga2CuO7 with the Yb2Fe3O7-type structure were obtained. In the In2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, or Zn), InGaFeO4, InGaNiO4, and InFeT MgO4 with the spinel structure, InGaZnO4, InGaMgO4, and InAl-CuO4 with the YbFe2O4-type structure, and In2Ga2MnO7 and In2Ga2ZnO7 with the Yb2Fe3O7-type structure were obtained. InGaMnO4 and InFe2O4 had both the YbFe2O4-type and spinel-type structures. The revised classification for the crystal structures of AB2O4 compounds is presented, based upon the coordination numbers of constituent A and B cations. 5 references, 2 tables.

Authors:
;
Publication Date:
Research Org.:
National Institute for Research in Inorganic Materials, Niiharigun, Japan
OSTI Identifier:
6198176
Resource Type:
Journal Article
Journal Name:
J. Solid State Chem.; (United States)
Additional Journal Information:
Journal Volume: 60
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ALUMINIUM OXIDES; CRYSTAL STRUCTURE; COPPER OXIDES; GALLIUM OXIDES; IRON OXIDES; MAGNESIUM OXIDES; MANGANESE OXIDES; NICKEL OXIDES; SCANDIUM OXIDES; ZINC OXIDES; CRYSTALLIZATION; EXPERIMENTAL DATA; LATTICE PARAMETERS; VERY HIGH TEMPERATURE; X-RAY DIFFRACTION; ALKALINE EARTH METAL COMPOUNDS; ALUMINIUM COMPOUNDS; CHALCOGENIDES; COHERENT SCATTERING; COPPER COMPOUNDS; DATA; DIFFRACTION; GALLIUM COMPOUNDS; INFORMATION; IRON COMPOUNDS; MAGNESIUM COMPOUNDS; MANGANESE COMPOUNDS; NICKEL COMPOUNDS; NUMERICAL DATA; OXIDES; OXYGEN COMPOUNDS; PHASE TRANSFORMATIONS; SCANDIUM COMPOUNDS; SCATTERING; TRANSITION ELEMENT COMPOUNDS; ZINC COMPOUNDS; 360202* - Ceramics, Cermets, & Refractories- Structure & Phase Studies

Citation Formats

Kimizuka, N., and Mohri, T.. Spinel, YbFe2O4, and Yb2Fe3O7 types of structure for compounds in the In2O3 and Sc2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, Cu, or Zn) at temperatures over 1000C. United States: N. p., 1985. Web. doi:10.1016/0022-4596(85)90290-7.
Kimizuka, N., & Mohri, T.. Spinel, YbFe2O4, and Yb2Fe3O7 types of structure for compounds in the In2O3 and Sc2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, Cu, or Zn) at temperatures over 1000C. United States. doi:10.1016/0022-4596(85)90290-7.
Kimizuka, N., and Mohri, T.. Tue . "Spinel, YbFe2O4, and Yb2Fe3O7 types of structure for compounds in the In2O3 and Sc2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, Cu, or Zn) at temperatures over 1000C". United States. doi:10.1016/0022-4596(85)90290-7.
@article{osti_6198176,
title = {Spinel, YbFe2O4, and Yb2Fe3O7 types of structure for compounds in the In2O3 and Sc2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, Cu, or Zn) at temperatures over 1000C},
author = {Kimizuka, N. and Mohri, T.},
abstractNote = {In the Sc2O3-Ga2O3-CuO, Sc2O3-Ga2O3-ZnO, and Sc2O3-Al2O3-CuO systems, ScGaCuO4, ScGaZnO4, and ScAlCuO4 with the YbFe2O4-type structure and Sc2Ga2CuO7 with the Yb2Fe3O7-type structure were obtained. In the In2O3-A2O3-BO systems (A: Fe, Ga, or Al; B: Mg, Mn, Fe, Ni, or Zn), InGaFeO4, InGaNiO4, and InFeT MgO4 with the spinel structure, InGaZnO4, InGaMgO4, and InAl-CuO4 with the YbFe2O4-type structure, and In2Ga2MnO7 and In2Ga2ZnO7 with the Yb2Fe3O7-type structure were obtained. InGaMnO4 and InFe2O4 had both the YbFe2O4-type and spinel-type structures. The revised classification for the crystal structures of AB2O4 compounds is presented, based upon the coordination numbers of constituent A and B cations. 5 references, 2 tables.},
doi = {10.1016/0022-4596(85)90290-7},
journal = {J. Solid State Chem.; (United States)},
number = ,
volume = 60,
place = {United States},
year = {1985},
month = {1}
}