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Title: Pulsed-field-gradient nuclear magnetic resonance spectrometer for direct measurement of ionic diffusion in solid electrolytes. Final report, 1 January 1985-31 December 1986

Abstract

A pulsed-field-gradient nuclear magnetic resonance spectrometer was successfully constructed, which is based on a superconducting magnet and has magic-angle spinning capabilities. A dewar facility is an integral part of this system so as to permit investigation of ionic diffusion down to 77 K, along with a sample heating arrangement for diffusion measurements up to 300 C. This spectrometer has been employed in the measurements of protonic diffusion coefficients in beta-alumina solid electrolytes and cation, anion, and self-diffusion coefficients and amorphous polymeric electrolytes.

Authors:
Publication Date:
Research Org.:
Northwestern Univ., Evanston, IL (USA)
OSTI Identifier:
6182741
Report Number(s):
AD-A-182211/3/XAB
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
47 OTHER INSTRUMENTATION; 25 ENERGY STORAGE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; NMR SPECTROMETERS; DESIGN; SOLID ELECTROLYTES; DIFFUSION; MAGNETS; POLYMERS; PULSES; SUPERCONDUCTORS; ELECTROLYTES; MEASURING INSTRUMENTS; SPECTROMETERS; 440300* - Miscellaneous Instruments- (-1989); 250903 - Energy Storage- Batteries- Materials, Components, & Auxiliaries; 420201 - Engineering- Cryogenic Equipment & Devices

Citation Formats

Whitmore, D H. Pulsed-field-gradient nuclear magnetic resonance spectrometer for direct measurement of ionic diffusion in solid electrolytes. Final report, 1 January 1985-31 December 1986. United States: N. p., 1987. Web.
Whitmore, D H. Pulsed-field-gradient nuclear magnetic resonance spectrometer for direct measurement of ionic diffusion in solid electrolytes. Final report, 1 January 1985-31 December 1986. United States.
Whitmore, D H. Fri . "Pulsed-field-gradient nuclear magnetic resonance spectrometer for direct measurement of ionic diffusion in solid electrolytes. Final report, 1 January 1985-31 December 1986". United States.
@article{osti_6182741,
title = {Pulsed-field-gradient nuclear magnetic resonance spectrometer for direct measurement of ionic diffusion in solid electrolytes. Final report, 1 January 1985-31 December 1986},
author = {Whitmore, D H},
abstractNote = {A pulsed-field-gradient nuclear magnetic resonance spectrometer was successfully constructed, which is based on a superconducting magnet and has magic-angle spinning capabilities. A dewar facility is an integral part of this system so as to permit investigation of ionic diffusion down to 77 K, along with a sample heating arrangement for diffusion measurements up to 300 C. This spectrometer has been employed in the measurements of protonic diffusion coefficients in beta-alumina solid electrolytes and cation, anion, and self-diffusion coefficients and amorphous polymeric electrolytes.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {1987},
month = {4}
}

Technical Report:
Other availability
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