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Title: New York State Department of Environmental Conservation PAMS monitoring system using a 3-column, double identification GC

Conference ·
OSTI ID:617624
; ;  [1]
  1. New York State Dept. of Environmental Conservation, Albany, NY (United States)

New York State conducted its 1995 PAMS measurements for New York City in the Bronx borough (New York Botanical Gardens) using a Perkin-Elmer ATD-400 Thermal Desorbtion Unit with an 8000 Series Gas Chromatograph. Data was collected in New York City, transferred to Albany, and processed in the central office. The system was checked on a daily basis from Albany to verify operation. Quality assurance for the system was provided by collecting a one hour collocated canister sample every day with analysis performed in Albany using a GC-MS system. The normal configuration for the Perkin-Elmer system uses only two columns, a PLOT column to separate low weight hydrocarbons (C{sub 2}-C{sub 5}) and a BP-1 column to separate higher weight hydrocarbons (C{sub 6}-C{sub 10}). New York`s custom designed system uses a third RTX-5 column to provide a second identification and quantitation of most target hydrocarbons. Analysis of the 1995 data provides insight into the usefulness of the third column in correcting both misidentified peaks and over-quantification of compound concentrations found using the standard configuration alone. The 1995 data set also allows an examination of the increased complexity versus the benefits of the system modification. 6 figs., 1 tab.

OSTI ID:
617624
Report Number(s):
CONF-9605175-; TRN: 98:002112-0004
Resource Relation:
Conference: International symposium on measurement of toxic and related air pollutants, Research Triangle Park, NC (United States), 7-10 May 1996; Other Information: PBD: 1996; Related Information: Is Part Of Measurement of toxic and related air pollutants; PB: 889 p.
Country of Publication:
United States
Language:
English

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