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Title: Bicyclobutadienylene(tricyclo(4. 2. 0. 0/sup 2/ /sup 5/)octa-1,3,5,7-tetraene)-eta/sup 5/-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-eta/sup 4/-cyclobutadiene-eta/sup 5/-cyclopentadienylcobalt

Abstract

It is reported that cobalt-complexed diethynylcyclobutadienes undergo a remarkable thermal rearrangement, the topological features of which suggest the intermediate formation of a cobalt-complexed biscyclobutadienylene moiety or its structural and electronic counterpart. (JSR)

Authors:
;
Publication Date:
Research Org.:
Univ. of California, Berkeley
OSTI Identifier:
6169062
Alternate Identifier(s):
OSTI ID: 6169062
Report Number(s):
CONF-790415-P1
Journal ID: CODEN: ACPCA
Resource Type:
Conference
Journal Name:
Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States)
Additional Journal Information:
Journal Volume: 24:1; Conference: 177. ACS national meeting, Honolulu, HI, USA, 1 Apr 1979
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; COBALT COMPLEXES; ISOMERIZATION; CYCLOALKENES; DIENES; ISOMERS; REACTION INTERMEDIATES; SUBLIMATION; ALKENES; CHEMICAL REACTIONS; COMPLEXES; EVAPORATION; HYDROCARBONS; ORGANIC COMPOUNDS; PHASE TRANSFORMATIONS; POLYENES; TRANSITION ELEMENT COMPLEXES 400301* -- Organic Chemistry-- Chemical & Physicochemical Properties-- (-1987); 400201 -- Chemical & Physicochemical Properties

Citation Formats

Fritch, J.R., and Vollhardt, K.P.C. Bicyclobutadienylene(tricyclo(4. 2. 0. 0/sup 2/ /sup 5/)octa-1,3,5,7-tetraene)-eta/sup 5/-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-eta/sup 4/-cyclobutadiene-eta/sup 5/-cyclopentadienylcobalt. United States: N. p., 1979. Web.
Fritch, J.R., & Vollhardt, K.P.C. Bicyclobutadienylene(tricyclo(4. 2. 0. 0/sup 2/ /sup 5/)octa-1,3,5,7-tetraene)-eta/sup 5/-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-eta/sup 4/-cyclobutadiene-eta/sup 5/-cyclopentadienylcobalt. United States.
Fritch, J.R., and Vollhardt, K.P.C. Thu . "Bicyclobutadienylene(tricyclo(4. 2. 0. 0/sup 2/ /sup 5/)octa-1,3,5,7-tetraene)-eta/sup 5/-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-eta/sup 4/-cyclobutadiene-eta/sup 5/-cyclopentadienylcobalt". United States.
@article{osti_6169062,
title = {Bicyclobutadienylene(tricyclo(4. 2. 0. 0/sup 2/ /sup 5/)octa-1,3,5,7-tetraene)-eta/sup 5/-cyclopentadienylcobalt. A possible intermediate in the remarkable gas phase rearrangement of 1,2-diethynyl-eta/sup 4/-cyclobutadiene-eta/sup 5/-cyclopentadienylcobalt},
author = {Fritch, J.R. and Vollhardt, K.P.C.},
abstractNote = {It is reported that cobalt-complexed diethynylcyclobutadienes undergo a remarkable thermal rearrangement, the topological features of which suggest the intermediate formation of a cobalt-complexed biscyclobutadienylene moiety or its structural and electronic counterpart. (JSR)},
doi = {},
journal = {Prepr., Div. Pet. Chem., Am. Chem. Soc.; (United States)},
number = ,
volume = 24:1,
place = {United States},
year = {1979},
month = {2}
}

Conference:
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