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Title: Thermal properties of quaternary ammonium and pyridinium compounds

Abstract

In the present work an attempt was made at a comprehensive investigation of the influence of the chemical structure of a whole series of cation-active surfactants on the stability to temperature influences, and the general directions of the irreversible transformations at high temperature were established. As a result of a study of processes of thermal decomposition of quaternary ammonium and syridinium salts, quantitative correlations were established according to the influence of the chemical structure of the salts on the limits of thermal stability. On the basis of a detailed analysis of volatile pyrolysis products, concrete schemes of the conversions in the objects studied were proposed.

Authors:
; ; ; ;
Publication Date:
OSTI Identifier:
6164491
Resource Type:
Journal Article
Journal Name:
J. Appl. Chem. USSR (Engl. Transl.); (United States)
Additional Journal Information:
Journal Volume: 55:6; Other Information: Translated from Zh. Prikl. Khim; 55: No.6, 1349-1356(Jun 1982)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; PYRIDINIUM COMPOUNDS; PYROLYSIS; THERMODYNAMIC PROPERTIES; QUATERNARY COMPOUNDS; SURFACTANTS; AMINES; AMMONIUM COMPOUNDS; AZINES; CHEMICAL REACTIONS; DECOMPOSITION; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; PHYSICAL PROPERTIES; PYRIDINES; THERMOCHEMICAL PROCESSES; 400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)

Citation Formats

Aksenova, V P, Khar'kov, S N, Logovotovskaya, V D, Belotserkovets, N I, and Chegolya, A S. Thermal properties of quaternary ammonium and pyridinium compounds. United States: N. p., 1982. Web.
Aksenova, V P, Khar'kov, S N, Logovotovskaya, V D, Belotserkovets, N I, & Chegolya, A S. Thermal properties of quaternary ammonium and pyridinium compounds. United States.
Aksenova, V P, Khar'kov, S N, Logovotovskaya, V D, Belotserkovets, N I, and Chegolya, A S. Fri . "Thermal properties of quaternary ammonium and pyridinium compounds". United States.
@article{osti_6164491,
title = {Thermal properties of quaternary ammonium and pyridinium compounds},
author = {Aksenova, V P and Khar'kov, S N and Logovotovskaya, V D and Belotserkovets, N I and Chegolya, A S},
abstractNote = {In the present work an attempt was made at a comprehensive investigation of the influence of the chemical structure of a whole series of cation-active surfactants on the stability to temperature influences, and the general directions of the irreversible transformations at high temperature were established. As a result of a study of processes of thermal decomposition of quaternary ammonium and syridinium salts, quantitative correlations were established according to the influence of the chemical structure of the salts on the limits of thermal stability. On the basis of a detailed analysis of volatile pyrolysis products, concrete schemes of the conversions in the objects studied were proposed.},
doi = {},
journal = {J. Appl. Chem. USSR (Engl. Transl.); (United States)},
number = ,
volume = 55:6,
place = {United States},
year = {1982},
month = {12}
}