Synthesis, characterization, and equilibria of palladium(II) nitrile, alkene, and heterometallacyclopentane complexes involved in metal nitro catalyzed alkene oxidation reactions

Journal Article · Wed Oct 03 00:00:00 EDT 1984 · J. Am. Chem. Soc.; (United States)

DOI:https://doi.org/10.1021/ja00332a027· OSTI ID:6139521

Andrews, M A; Chang, T C.T.; Cheng, C W.F.; Emge, T J; Kelly, K P; Koetzle, T F

The synthesis and characterization of representative examples of palladium(II) nitrile, alkene, and heterometallacyclopentane complexes are described in detail. These complexes are all in rapid equilibrium with each other under the reaction conditions examined. Although quantitative data regarding the equilibria are not obtainable, qualitative kinetic and thermodynamic observations are presented that are relevant to the extensive Pd(II)-mediated chemistry of alkenes. Typical metallacycles are also involved in bridge cleavage and possible ring-opening equilibria.

• Research Organization: Brookhaven National Lab., Upton, NY
• OSTI ID: 6139521
• Journal Information: J. Am. Chem. Soc.; (United States), Vol. 106:20
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKENES
CHEMICAL PREPARATION
OXIDATION
CYCLOALKENES
NITRILES
PALLADIUM COMPLEXES
EXPERIMENTAL DATA
ORGANOMETALLIC COMPOUNDS
CHEMICAL REACTIONS
COMPLEXES
DATA
HYDROCARBONS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
SYNTHESIS
TRANSITION ELEMENT COMPLEXES
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
400201 - Chemical & Physicochemical Properties