Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts

Beer, R H; Jimenez, J; Drago, R S

doi:10.1021/jo00059a024

Title: Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts

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Abstract

Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known [alpha]-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines. The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro-and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts. 7 refs., 1 fig.

Authors:

Beer, R H; Jimenez, J; Drago, R S ^[1]

Univ. of Florida, Gainesville (United States)

Publication Date:: Fri Mar 26 00:00:00 EST 1993

OSTI Identifier:: 6078897

Resource Type:: Journal Article

Journal Name:: Journal of Organic Chemistry; (United States)

Additional Journal Information:: Journal Volume: 58:7; Journal ID: ISSN 0022-3263

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CATALYSTS; CHEMICAL PREPARATION; PHENANTHROLINES; LIGANDS; METALS; OXIDATION; RADICALS; AROMATICS; AZAARENES; CHEMICAL REACTIONS; ELEMENTS; HETEROCYCLIC COMPOUNDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; SYNTHESIS; 400201* - Chemical & Physicochemical Properties

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                    Beer, R H, Jimenez, J, and Drago, R S. Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts.  United States: N. p., 1993. 
        Web.  doi:10.1021/jo00059a024.

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                    Beer, R H, Jimenez, J, & Drago, R S. Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts.  United States.  https://doi.org/10.1021/jo00059a024

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                    Beer, R H, Jimenez, J, and Drago, R S. 1993.  
        "Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts".  United States.  https://doi.org/10.1021/jo00059a024.

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@article{osti_6078897,

  title        = {Syntheses of 2,9-bis(halomethyl)-1,10-phenanthrolines: Potential robust ligands for metal oxidation catalysts},

  author       = {Beer, R H and Jimenez, J and Drago, R S},

  abstractNote = {Free radical halogenation of 2,9-dimethyl-1,10-phenanthroline with N-bromosuccinimide and N-chlorosuccinimide form the known [alpha]-methyl derivatives 2,9-bis(trihalomethyl)-1,10-phenanthrolines. The compound 2,9-bis(trichloromethyl)-1,10-phenanthroline can be used for one-step syntheses of oxidatively resistant fluoro-and partially reduced chloromethyl derivatives capable of coordination to metal oxidation catalysts. 7 refs., 1 fig.},

  doi          = {10.1021/jo00059a024},

  url          = {https://www.osti.gov/biblio/6078897},
  journal      = {Journal of Organic Chemistry; (United States)},

  issn         = {0022-3263},

  number       = ,

  volume       = 58:7,

  place        = {United States},

  year         = {Fri Mar 26 00:00:00 EST 1993},

  month        = {Fri Mar 26 00:00:00 EST 1993}

}

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https://doi.org/10.1021/jo00059a024

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