Direct fluorination of nitrogen-containing ladder polymers, two new [open quotes]graphitic[close quotes] fluorocarbon polymers

Journal Article · Thu Apr 01 00:00:00 EST 1993 · Chemistry of Materials; (United States)

DOI:https://doi.org/10.1021/cm00028a005· OSTI ID:6045435

Kampa, J J; Lagow, R J ^[1]

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1. Univ. of Texas, Austin (United States)

Paracyanogen and pyrolyzed poly(acrylonitrile) have been perfluorinated using elemental fluorine and have retained their polymeric fused ring structures. The two new materials produced by this method were characterized by infrared spectroscopy, electron impact mass spectrometry, elemental analysis, iodometric titration, and thermogravimetric analysis. Some chemical and physical properties are discussed as well as several possible applications in light of the discussed properties of these materials. 21 refs., 4 figs., 3 tabs.

• DOE Contract Number: FG05-91ER12119
• OSTI ID: 6045435
• Journal Information: Chemistry of Materials; (United States), Vol. 5:4; ISSN 0897-4756
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
ORGANIC NITROGEN COMPOUNDS
FLUORINATION
ORGANIC POLYMERS
ABSORPTION SPECTROSCOPY
ACRYLONITRILE
CHEMICAL ANALYSIS
CHEMICAL COMPOSITION
FLUORINE
IODOMETRY
MASS SPECTROSCOPY
PHYSICAL PROPERTIES
TEMPERATURE DEPENDENCE
TEMPERATURE RANGE 0273-0400 K
TEMPERATURE RANGE 0400-1000 K
THERMAL GRAVIMETRIC ANALYSIS
USES
CHEMICAL REACTIONS
ELEMENTS
GRAVIMETRIC ANALYSIS
HALOGENATION
HALOGENS
NITRILES
NONMETALS
ORGANIC COMPOUNDS
POLYMERS
QUANTITATIVE CHEMICAL ANALYSIS
SPECTROSCOPY
TEMPERATURE RANGE
THERMAL ANALYSIS
TITRATION
400201* - Chemical & Physicochemical Properties
360606 - Other Materials- Physical Properties- (1992-)