Excited states of mixed-ligand chelates of ruthenium. II. Quantum yield and decay time measurements
Journal Article
·
· J. Am. Chem. Soc.; (United States)
The photoluminescence of a series of (Ru(II)(bpy)/sub m/(N-N)/sub n/)/sup 2 +/ cations (m = 3 - n; n = 0, 1, 2, 3; bpy = 2,2'-bipyridine; N-N = 1,10-phenanthroline (phen) or substituted phen or substituted bpy) was investigated. All compounds displayed a prominent visible luminescence, a single approx. 1.3 kK vibration progression, and an approx. 5 ..mu..s decay time at 77/sup 0/K that increased monotonoically as the temperature was lowered. Quantum yields at 77/sup 0/K ranged between 0.35 and 0.58. The data were analyzed in terms of a charge-transfer-to-ligand excited manifold of three levels.
- Research Organization:
- Washington State Univ., Pullman
- OSTI ID:
- 6040351
- Journal Information:
- J. Am. Chem. Soc.; (United States), Vol. 103:10
- Country of Publication:
- United States
- Language:
- English
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Wed Jun 29 00:00:00 EDT 1988
· Inorg. Chem.; (United States)
·
OSTI ID:6040351
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Journal Article
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· J. Am. Chem. Soc.; (United States)
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Ruthenium Bis-diimine Complexes with a Chelating Thioether Ligand: Delineating 1,10-Phenanthrolinyl and 2,2'-Bipyridyl Ligand Substituent Effects
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
08 HYDROGEN
BIPYRIDINES
LUMINESCENCE
PHOTOCHEMICAL REACTIONS
PHENANTHROLINES
RUTHENIUM COMPLEXES
EXCITED STATES
WATER
DECOMPOSITION
CATALYSIS
CATALYTIC EFFECTS
CHELATES
EXPERIMENTAL DATA
HYDROGEN PRODUCTION
AZINES
CHEMICAL REACTIONS
COMPLEXES
DATA
ENERGY LEVELS
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PYRIDINES
TRANSITION ELEMENT COMPLEXES
400500* - Photochemistry
080106 - Hydrogen- Production- Biosynthesis & Photochemical Processes
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
08 HYDROGEN
BIPYRIDINES
LUMINESCENCE
PHOTOCHEMICAL REACTIONS
PHENANTHROLINES
RUTHENIUM COMPLEXES
EXCITED STATES
WATER
DECOMPOSITION
CATALYSIS
CATALYTIC EFFECTS
CHELATES
EXPERIMENTAL DATA
HYDROGEN PRODUCTION
AZINES
CHEMICAL REACTIONS
COMPLEXES
DATA
ENERGY LEVELS
HETEROCYCLIC COMPOUNDS
HYDROGEN COMPOUNDS
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PYRIDINES
TRANSITION ELEMENT COMPLEXES
400500* - Photochemistry
080106 - Hydrogen- Production- Biosynthesis & Photochemical Processes