Hydrogen speciation in hydrated layers on nuclear waste glass
The hydration of an outer layer on nuclear waste glasses in known to occur during leaching, but the actual speciation of hydrogen (as water or hydroxyl groups) in these layers has not been determined. As part of the Nevada Nuclear Waste Storage Investigations Project, we have used infrared spectroscopy to determine hydrogen speciations in three nuclear waste glass compositions (SRL-131 & 165, and PNL 76-68), which were leached at 90{sup 0}C (all glasses) or hydrated in a vapor-saturated atmosphere at 202{sup 0}C (SRL-131 only). Hydroxyl groups were found in the surface layers of all the glasses. In addition, molecular water was found in the surface of SRL-131 and PNL 76-68 glasses that had been leached for several months in deionized water, and in the vapor-hydrated sample. The water/hydroxyl ratio increases with increasing reaction time; molecular water makes up most of the hydrogen in the thick reaction layers on vapor-phase hydrated glass while only hydroxyl occurs in the least reacted samples. The hydrated layer on the nuclear waste glasses appears to be of relatively low water content (4 to 7% by weight) and is not substantially hydroxylated. Thus, these layers do not have many of the properties associated with gel layers.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
- DOE Contract Number:
- W-7405-ENG-48
- OSTI ID:
- 60124
- Report Number(s):
- CONF-861207-Pt.1; ON: TI87009337
- Resource Relation:
- Conference: Materials Research Society (MRS) fall meeting, Boston, MA (United States), 1-5 Dec 1986; Other Information: PBD: 1987; Related Information: Is Part Of Scientific basis for Nuclear Waste Management X; Bates, J.K.; Seefeldt, W.B. (eds.); PB: 547-558 p.
- Country of Publication:
- United States
- Language:
- English
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