Mechanism of the gas-phase thermal oxidation of ethylene. II. Chain propagation and formation of reaction products. [Ethyl peroxide radicals; ethyl radicals]
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:6011502
A sequence of elementary events explaining chain propagation and the formation of the reaction products of the gas-phase oxidation of ethylene was proposed on the basis of the experimental data on the kinetics of accumulation of RO/sub 2/ and HO/sub 2/ radicals and molecular reaction products. In this work, on the basis of the experimental data on the principle of the accumulation of radicals and molecular reaction products, the elementary processes in which the active sites that may determine chain propagation and the formation of the reaction products participate are analyzed and discussed.
- Research Organization:
- Academy of Sciences of the Armenian SSR, Ervan, USSR
- OSTI ID:
- 6011502
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Vol. 22:6
- Country of Publication:
- United States
- Language:
- English
Similar Records
Kinetic analysis of HO{sub 2} addition to ethylene, propene, and isobutene, and thermochemical parameters of alkyl hydroperoxides and hydroperoxide alkyl radicals
Reaction of hydroperoxy t-butyl radicals and t-butyl peroxy t-butyl radicals in relation to chain propagation in combustion
Low Temperature Chlorine-Initiated Oxidation of Small-Chain Methyl Esters: Quantification of Chain-Terminating HO2-Elimination Channels
Journal Article
·
Thu Jun 01 00:00:00 EDT 2000
· Journal of Physical Chemistry A: Molecules, Spectroscopy, Kinetics, Environment, amp General Theory
·
OSTI ID:6011502
Reaction of hydroperoxy t-butyl radicals and t-butyl peroxy t-butyl radicals in relation to chain propagation in combustion
Book
·
Sat Dec 31 00:00:00 EST 1994
·
OSTI ID:6011502
Low Temperature Chlorine-Initiated Oxidation of Small-Chain Methyl Esters: Quantification of Chain-Terminating HO2-Elimination Channels
Journal Article
·
Wed Feb 24 00:00:00 EST 2016
· Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory
·
OSTI ID:6011502
+2 more
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ETHYLENE
OXIDATION
RADICALS
CHEMICAL REACTION YIELD
CHEMICAL REACTION KINETICS
ALKENES
CHEMICAL REACTIONS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
REACTION KINETICS
YIELDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ETHYLENE
OXIDATION
RADICALS
CHEMICAL REACTION YIELD
CHEMICAL REACTION KINETICS
ALKENES
CHEMICAL REACTIONS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
REACTION KINETICS
YIELDS
400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)