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Title: Adsorptive heat recovery drying system

Journal Article · · Chem. Eng. Prog.; (United States)
OSTI ID:5944330

The adsorptive heat recovery (AHR) drying system has been developed by Union Carbide Corp. for energy-efficient drying of petrochemical streams containing substantial amounts of water. Using the ethanol-water azeotrope as an example, it was shown that the AHR drying technology provides an energy-efficient adsorption process alternative to azeotropic and extractive distillation for the dehydration of organic-water azeotropes. The key features of the AHR drying cycle are: 1) the AHR cycle is an energy-efficient adsorption method for drying high water content streams that uses only a fraction of the energy required by conventional thermal swing adsorption/regeneration schemes. 2) all of the heat of adsorption is stored substantially during the adsorption step. 3) stored adsorptive heat is used to supply regeneration energy during the desorption step. This reduces the volume and temperature of purge gas required. 4) unique properties of Union Carbide molecular sieves are utilized. 5) use of fixed bed adsorption is extended from <3% water content to up to 20% or more water content streams. The AHR drying system has been in commercial use for upgrading 190 proof ethanol to 199/sup +/ proof ethanol for over a year. AHR technology is of wide utility in the general area of drying of organic-water azeotropes and of other petrochemical streams containing substantial amounts of water.

Research Organization:
Union Carbide Corp., Tarrytown, NY 10591
OSTI ID:
5944330
Journal Information:
Chem. Eng. Prog.; (United States), Vol. 82:2
Country of Publication:
United States
Language:
English