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Title: Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] with bidentate phosphine ligands

Abstract

Reactions of the unsaturated cluster [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] (1) with the bidentate 1,n-bis(diphenylphosphino)alkanes (CH[sub 2])[sub n](PPh[sub 2])[sub 2], where n = 1--3 (abbreviated as dppm, dppe, and dppp, respectively), have been studied. The species have been characterized by NMR and mass spectrometry, and crystal structure determinations are described.

Authors:
; ;  [1]
  1. (Univ. of Missouri, St. Louis, MO (United States). Dept. of Chemistry)
Publication Date:
Sponsoring Org.:
National Science Foundation (NSF); USDOE; National Institutes of Health (NIH); National Science Foundation, Washington, DC (United States); USDOE, Washington, DC (United States); National Insts. of Health, Bethesda, MD (United States)
OSTI Identifier:
5937113
DOE Contract Number:  
FG02-92CH10499
Resource Type:
Journal Article
Journal Name:
Organometallics
Additional Journal Information:
Journal Volume: 18:18; Journal ID: ISSN 0276-7333
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; BORANES; CRYSTAL STRUCTURE; LIGANDS; ORGANIC SULFUR COMPOUNDS; ORGANOMETALLIC COMPOUNDS; PHOSPHINES; BORON COMPOUNDS; HYDRIDES; HYDROGEN COMPOUNDS; ORGANIC COMPOUNDS; PHOSPHORUS COMPOUNDS; 400201* - Chemical & Physicochemical Properties

Citation Formats

Macias, R., Rath, N.P., and Barton, L. Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] with bidentate phosphine ligands. United States: N. p., 1999. Web. doi:10.1021/om9901168.
Macias, R., Rath, N.P., & Barton, L. Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] with bidentate phosphine ligands. United States. doi:10.1021/om9901168.
Macias, R., Rath, N.P., and Barton, L. Mon . "Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] with bidentate phosphine ligands". United States. doi:10.1021/om9901168.
@article{osti_5937113,
title = {Organometallic chemistry on a metallathiaborane cluster: Reactions of [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] with bidentate phosphine ligands},
author = {Macias, R. and Rath, N.P. and Barton, L.},
abstractNote = {Reactions of the unsaturated cluster [8,8-(PPh[sub 3])[sub 2]-nido-8,7-RhSB[sub 9]H[sub 10]] (1) with the bidentate 1,n-bis(diphenylphosphino)alkanes (CH[sub 2])[sub n](PPh[sub 2])[sub 2], where n = 1--3 (abbreviated as dppm, dppe, and dppp, respectively), have been studied. The species have been characterized by NMR and mass spectrometry, and crystal structure determinations are described.},
doi = {10.1021/om9901168},
journal = {Organometallics},
issn = {0276-7333},
number = ,
volume = 18:18,
place = {United States},
year = {1999},
month = {8}
}