Extraction of antimony from nitric acid solutions using tributyl phosphate. I. Tributyl phosphate-antimony(III)-nitric acid system

Journal Article · Sun Jan 01 00:00:00 EST 1989 · Sov. Radiochem. (Engl. Transl.); (United States)

OSTI ID:5913736

Lakaev, V S; Smelov, V S

Experimental data have been reported concerning the extraction of trivalent antimony from nitric acid solutions using tributyl phosphate (TBP). A possible mechanism for the extraction of antimony(III) has been determined and the (pre)concentration constant for the process has been calculated. The effect of temperature on trivalent antimony extraction has also been evaluated. The enthalpy value and standard isobar potential and entropy for this process have been determined.

• OSTI ID: 5913736
• Journal Information: Sov. Radiochem. (Engl. Transl.); (United States), Vol. 30:3; Other Information: Translated from Radiokhimiya; 30: No. 3, 355-358(May-Jun 1988)
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ANTIMONY 125
ISOTOPE SEPARATION
ANTIMONY COMPOUNDS
SOLVENT EXTRACTION
TBP
SOLVENT PROPERTIES
CHEMICAL REACTION KINETICS
DISSOLUTION
ENTROPY
EQUATIONS
HYDROGEN COMPOUNDS
MASS DISTRIBUTION
NITRIC ACID
QUANTITY RATIO
SOLUBILITY
SOLUTION HEAT
TEMPERATURE DEPENDENCE
VALENCE
ANTIMONY ISOTOPES
BETA DECAY RADIOISOTOPES
BETA-MINUS DECAY RADIOISOTOPES
BUTYL PHOSPHATES
DISTRIBUTION
ENTHALPY
ESTERS
EXTRACTION
INORGANIC ACIDS
INTERMEDIATE MASS NUCLEI
ISOTOPES
KINETICS
NUCLEI
ODD-EVEN NUCLEI
ORGANIC COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
PHOSPHORIC ACID ESTERS
PHYSICAL PROPERTIES
RADIOISOTOPES
REACTION KINETICS
SEPARATION PROCESSES
SPATIAL DISTRIBUTION
THERMODYNAMIC PROPERTIES
YEARS LIVING RADIOISOTOPES
400201* - Chemical & Physicochemical Properties
400202 - Isotope Effects
Isotope Exchange
& Isotope Separation