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Title: NO{sub x} from lightning 1. Global distribution based on lightning physics

Journal Article · · Journal of Geophysical Research
DOI:https://doi.org/10.1029/96JD03504· OSTI ID:587206
 [1];  [1];  [2]
  1. Atmospheric Science Division, Lawrence Livermore National Laboratory, Livermore, California (United States)
  2. Department of Earth System Science, University of California, Irvine (United States)

This paper begins a study on the role of lightning in maintaining the global distribution of nitrogen oxides (NO{sub x}) in the troposphere. It presents the first global and seasonal distributions of lightning-produced NO{sub x} (LNO{sub x}) based on the observed distribution of electrical storms and the physical properties of lightning strokes. We derive a global rate for cloud-to-ground (CG) flashes of 20{endash}30 flashes/s with a mean energy per flash of 6.7{times}10{sup 9}J. Intracloud (IC) flashes are more frequent, 50{endash}70 flashes/s but have 10{percent} of the energy of CG strokes and, consequently, produce significantly less NO{sub x}. It appears to us that the majority of previous studies have mistakenly assumed that all lightning flashes produce the same amount of NO{sub x}, thus overestimating the NO{sub x} production by a factor of 3. On the other hand, we feel these same studies have underestimated the energy released in CG flashes, resulting in two negating assumptions. For CG energies we adopt a production rate of 10{times}10{sup 16} molecules NO/J based on the current literature. Using a method to simulate global lightning frequencies from satellite-observed cloud data, we have calculated the LNO{sub x} on various spatial (regional, zonal, meridional, and global) and temporal scales (daily, monthly, seasonal, and interannual). Regionally, the production of LNO{sub x} is concentrated over tropical continental regions, predominantly in the summer hemisphere. The annual mean production rate is calculated to be 12.2 Tg N/yr, and we believe it extremely unlikely that this number is less than 5 or more than 20 Tg N/yr. Although most of LNO{sub x} is produced in the lowest 5 km by CG lightning, convective mixing in the thunderstorms is likely to deposit large amounts of NO{sub x} in the upper troposphere where it is important in ozone production. (Abstract Truncated)

OSTI ID:
587206
Journal Information:
Journal of Geophysical Research, Vol. 102, Issue D5; Other Information: PBD: Mar 1997
Country of Publication:
United States
Language:
English

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