The Role of Oxygen in the Copper-Catalyzed Decomposition of Phenylborates in Aqueous Alkaline Solutions
- Westinghouse Savannah River Company, AIKEN, SC (United States)
The effect of oxygen on the copper-catalyzed hydrolysis of phenyl borates containing from one to four phenyl groups was studied in 1 M aqueous sodium hydroxide solution at 59 degrees C. The results are tentatively explained if the effective catalyst for each of the reactions is either cupric or cuprous ion, with the latter being present in significant concentration only in the absence of air.
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States)
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- AC09-96SR18500
- OSTI ID:
- 585000
- Report Number(s):
- WSRC-TR-97-0069; ON: DE98052142
- Resource Relation:
- Other Information: PBD: 17 Mar 1997
- Country of Publication:
- United States
- Language:
- English
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