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Title: Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of carbamic ester from carbon dioxide, amine, and epoxide

Abstract

Carbon dioxide is trapped by (5,10,15,20-tetraphenylporphinato) aluminum acetate in the presence of a secondary amine in the form of an aluminum carbamate on the opposite side to the acetate group with respect to the porphyrin plane. Carbon dioxide thus trapped by aluminum porphyrin is activated enough to undergo a catalytic reaction involving secondary amine and epoxide to afford dialkylcarbamic ester under atmospheric pressure at room temperature. 15 references, 2 figures, 2 tables.

Authors:
; ;
Publication Date:
Research Org.:
Univ. of Tokyo, Japan
OSTI Identifier:
5826848
Resource Type:
Journal Article
Journal Name:
J. Am. Chem. Soc.; (United States)
Additional Journal Information:
Journal Volume: 108:3
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACETATES; CATALYTIC EFFECTS; ALUMINIUM; AMINES; CHEMICAL REACTIONS; CARBAMIC ACID ESTERS; CHEMICAL PREPARATION; CARBON DIOXIDE; CARBON DIOXIDE FIXATION; EFFICIENCY; EPOXIDES; PORPHYRINS; ATMOSPHERIC PRESSURE; CATALYSIS; CATALYSTS; EXPERIMENTAL DATA; MEDIUM TEMPERATURE; NMR SPECTRA; CARBON COMPOUNDS; CARBON OXIDES; CARBOXYLIC ACID ESTERS; CARBOXYLIC ACID SALTS; CARBOXYLIC ACIDS; CHALCOGENIDES; DATA; ELEMENTS; ESTERS; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; INFORMATION; METALS; NUMERICAL DATA; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; OXIDES; OXYGEN COMPOUNDS; SPECTRA; SYNTHESIS; 400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)

Citation Formats

Kojima, F, Aida, T, and Inoue, S. Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of carbamic ester from carbon dioxide, amine, and epoxide. United States: N. p., 1986. Web. doi:10.1021/ja00263a008.
Kojima, F, Aida, T, & Inoue, S. Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of carbamic ester from carbon dioxide, amine, and epoxide. United States. doi:10.1021/ja00263a008.
Kojima, F, Aida, T, and Inoue, S. Wed . "Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of carbamic ester from carbon dioxide, amine, and epoxide". United States. doi:10.1021/ja00263a008.
@article{osti_5826848,
title = {Fixation and activation of carbon dioxide on aluminum porphyrin. Catalytic formation of carbamic ester from carbon dioxide, amine, and epoxide},
author = {Kojima, F and Aida, T and Inoue, S},
abstractNote = {Carbon dioxide is trapped by (5,10,15,20-tetraphenylporphinato) aluminum acetate in the presence of a secondary amine in the form of an aluminum carbamate on the opposite side to the acetate group with respect to the porphyrin plane. Carbon dioxide thus trapped by aluminum porphyrin is activated enough to undergo a catalytic reaction involving secondary amine and epoxide to afford dialkylcarbamic ester under atmospheric pressure at room temperature. 15 references, 2 figures, 2 tables.},
doi = {10.1021/ja00263a008},
journal = {J. Am. Chem. Soc.; (United States)},
number = ,
volume = 108:3,
place = {United States},
year = {1986},
month = {2}
}