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Title: Radiation curable adhesive compositions and composite structures

Abstract

This disclosure relates to novel adhesive compositions and composite structures utilizing the same, wherein said adhesive compositions contain an elastomer, a chemically compatible ethylenically unsaturated monomer, a tackifier, an adhesion promoter, and optionally, pigments, fillers, thickeners and flow control agents which are converted from the liquid to the solid state by exposure to high energy ionizing radiation such as electron beam. A particularly useful application for such adhesive compositions comprises the assembly of certain composite structures or laminates consisting of, for example, a fiber flocked rubber sheet and a metal base with the adhesive fulfilling the multiple functions of adhering the flocked fiber to the rubber sheet as well as adhering the rubber sheet to the metal base. Optionally, the rubber sheet itself may also be cured at the same time as the adhesive composition with all operations being carried out at ambient temperatures and in the presence of air, with exposure of said assembly to selected dosages of high energy ionizing radiation. These adhesive compositions contain no solvents thereby almost eliminating air pollution or solvent toxicity problems, and offer substantial savings in energy and labor as they are capable of curing in very short time periods without the usemore » of external heat which might damage the substrate.« less

Inventors:
Publication Date:
OSTI Identifier:
5813848
Patent Number(s):
US 4483951
Assignee:
The Standard Products Company
Resource Type:
Patent
Resource Relation:
Patent File Date: Filed date 2 Dec 1981; Other Information: PAT-APPL-326903
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ADHESIVES; CHEMICAL COMPOSITION; CHEMICAL PREPARATION; IONIZATION; IRRADIATION; RADIATION CURING; AIR POLLUTION ABATEMENT; CHEMICAL BONDS; COMPOSITE MATERIALS; ELECTRON BEAMS; ETHYLENE; FILLERS; MONOMERS; RADIATION DOSES; RADIATION EFFECTS; RUBBERS; ALKENES; BEAMS; CHEMICAL RADIATION EFFECTS; CHEMISTRY; CURING; DOSES; ELASTOMERS; HYDROCARBONS; LEPTON BEAMS; MATERIALS; ORGANIC COMPOUNDS; ORGANIC POLYMERS; PARTICLE BEAMS; POLLUTION ABATEMENT; POLYMERS; RADIATION CHEMISTRY; SYNTHESIS; 360406* - Materials- Polymers & Plastics- Radiation Effects- (-1987)

Citation Formats

Brenner, W. Radiation curable adhesive compositions and composite structures. United States: N. p., 1984. Web.
Brenner, W. Radiation curable adhesive compositions and composite structures. United States.
Brenner, W. 1984. "Radiation curable adhesive compositions and composite structures". United States.
@article{osti_5813848,
title = {Radiation curable adhesive compositions and composite structures},
author = {Brenner, W},
abstractNote = {This disclosure relates to novel adhesive compositions and composite structures utilizing the same, wherein said adhesive compositions contain an elastomer, a chemically compatible ethylenically unsaturated monomer, a tackifier, an adhesion promoter, and optionally, pigments, fillers, thickeners and flow control agents which are converted from the liquid to the solid state by exposure to high energy ionizing radiation such as electron beam. A particularly useful application for such adhesive compositions comprises the assembly of certain composite structures or laminates consisting of, for example, a fiber flocked rubber sheet and a metal base with the adhesive fulfilling the multiple functions of adhering the flocked fiber to the rubber sheet as well as adhering the rubber sheet to the metal base. Optionally, the rubber sheet itself may also be cured at the same time as the adhesive composition with all operations being carried out at ambient temperatures and in the presence of air, with exposure of said assembly to selected dosages of high energy ionizing radiation. These adhesive compositions contain no solvents thereby almost eliminating air pollution or solvent toxicity problems, and offer substantial savings in energy and labor as they are capable of curing in very short time periods without the use of external heat which might damage the substrate.},
doi = {},
url = {https://www.osti.gov/biblio/5813848}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Nov 20 00:00:00 EST 1984},
month = {Tue Nov 20 00:00:00 EST 1984}
}