Two-stage production of olefins utilizing a faujasite structure zeolite in hydrogenation stage
A process is disclosed for the production of olefins in two stages. In the first stage, heavy petroleum fractions are hydrogenated in the presence of hydrogen and a hydrogenation catalyst and, in the second stage, the thus-hydrogenated fractions are subjected to thermal cracking the presence of steam. The improvement comprises employing as the hydrogenation catalyst a zeolite of the faujasite structure combined with elements from groups VIB, VIIB and VIII of the periodic table of the elements, wherein the alkali component of the zeolite is exchanged at least partially for ammonium, hydronium, alkaline earth and/or rare earth ions, and the elements are present in a metallic, ionic, oxidic and/or sulfidic form.
- Assignee:
- Bayer Ag (Germany, Federal Republic of); Linde Ag (Germany, Federal Republic Of)
- Patent Number(s):
- US 4188281
- OSTI ID:
- 5705919
- Resource Relation:
- Patent Priority Date: Priority date 12 May 1977, German, Federal Republic of (F.R. Germany); Other Information: PAT-APPL-905486
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
FAUJASITE
CHEMICAL COMPOSITION
HYDROGENATION
CATALYSTS
PETROLEUM FRACTIONS
ALKALINE EARTH METAL COMPOUNDS
ALKENES
AMMONIUM COMPOUNDS
OXONIUM IONS
RARE EARTH COMPOUNDS
THERMAL CRACKING
ZEOLITES
CHARGED PARTICLES
CHEMICAL REACTIONS
CRACKING
DECOMPOSITION
ENERGY SOURCES
FOSSIL FUELS
FUELS
HYDROCARBONS
INORGANIC ION EXCHANGERS
ION EXCHANGE MATERIALS
IONS
MATERIALS
MINERALS
MOLECULAR IONS
ORGANIC COMPOUNDS
PETROLEUM
PYROLYSIS
THERMOCHEMICAL PROCESSES
020400* - Petroleum- Processing