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Title: Excess enthalpies of the binary system methane-hydrogen sulfide by flow calorimetry

Abstract

Enthalpies of mixing for the binary gaseous system methane-hydrogen sulfide were measured by an isothermal flow calorimeter at temperatures of 293.15, 305.15, and 313.15 K. For each isotherm, the measurements were made at pressures of 0.507, 1.013, and 1.520 MPa (5, 10, and 15 atm, respectively). The experimental results were compared with those predicted from the equation of state of Benedict-Webb-Rubin and Redlich-Kwong and the Redlich-Kwong equation with the modifications proposed by Jacoby and Robinson.

Authors:
; ;
Publication Date:
Research Org.:
Department of Chemical Engineering, Laval University, Ste-Foy, Quebec, G1K 7P4
OSTI Identifier:
5683017
Resource Type:
Journal Article
Journal Name:
J. Chem. Eng. Data; (United States)
Additional Journal Information:
Journal Volume: 27:4
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 03 NATURAL GAS; HYDROGEN SULFIDES; CALORIMETRY; ENTHALPY; METHANE; BINARY MIXTURES; EQUATIONS OF STATE; GASES; ISOTHERMAL PROCESSES; MIXING; PRESSURE DEPENDENCE; TEMPERATURE DEPENDENCE; ALKANES; CHALCOGENIDES; DISPERSIONS; EQUATIONS; FLUIDS; HYDROCARBONS; HYDROGEN COMPOUNDS; MIXTURES; ORGANIC COMPOUNDS; PHYSICAL PROPERTIES; SULFIDES; SULFUR COMPOUNDS; THERMODYNAMIC PROPERTIES; 400301* - Organic Chemistry- Chemical & Physicochemical Properties- (-1987); 033000 - Natural Gas- Properties & Composition; 400201 - Chemical & Physicochemical Properties

Citation Formats

Barry, A O, Kallaguine, S C, and Ramalho, R S. Excess enthalpies of the binary system methane-hydrogen sulfide by flow calorimetry. United States: N. p., 1982. Web. doi:10.1021/je00030a020.
Barry, A O, Kallaguine, S C, & Ramalho, R S. Excess enthalpies of the binary system methane-hydrogen sulfide by flow calorimetry. United States. https://doi.org/10.1021/je00030a020
Barry, A O, Kallaguine, S C, and Ramalho, R S. Fri . "Excess enthalpies of the binary system methane-hydrogen sulfide by flow calorimetry". United States. https://doi.org/10.1021/je00030a020.
@article{osti_5683017,
title = {Excess enthalpies of the binary system methane-hydrogen sulfide by flow calorimetry},
author = {Barry, A O and Kallaguine, S C and Ramalho, R S},
abstractNote = {Enthalpies of mixing for the binary gaseous system methane-hydrogen sulfide were measured by an isothermal flow calorimeter at temperatures of 293.15, 305.15, and 313.15 K. For each isotherm, the measurements were made at pressures of 0.507, 1.013, and 1.520 MPa (5, 10, and 15 atm, respectively). The experimental results were compared with those predicted from the equation of state of Benedict-Webb-Rubin and Redlich-Kwong and the Redlich-Kwong equation with the modifications proposed by Jacoby and Robinson.},
doi = {10.1021/je00030a020},
url = {https://www.osti.gov/biblio/5683017}, journal = {J. Chem. Eng. Data; (United States)},
number = ,
volume = 27:4,
place = {United States},
year = {1982},
month = {10}
}