Possibility of metallic intercalation of transition-metal dichalcogenide crystals during their growth from vapor phase
The proper thermodynamic characteristics of vapor-transport systems, used for simultaneous processes of growth and intercalation of layered crystals, may be determined directly from tensimetric investigations of heterogeneous equilibria in dichalcogenide layered structure-intercalating metal-transport agent systems. It serves the purpose of optimizing the deposition conditions of intercalates from the vapor phase. Investigation of the simultaneous growth and intercalation processes of layered crystals reveals the possibility of producing layered crystals with alternate layers of intercalating metals in streaming vapor-transport systems and of creating different physical properties in the bulk of the matrix through sandwiching.
- OSTI ID:
- 5679839
- Journal Information:
- Inorg. Mater. (Engl. Transl.); (United States), Vol. 23:4; Other Information: Translated from Izv. Akad. Nauk SSSR, Neorg. Mater.; 23: No. 4, 550-553(Apr 1987)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
CHALCOGENIDES
CHEMICAL VAPOR DEPOSITION
VAPOR PHASE EPITAXY
IODIDES
TRANSITION ELEMENT COMPOUNDS
CLATHRATES
CRYSTALLIZATION
MATHEMATICAL MODELS
OPTIMIZATION
PARTIAL PRESSURE
PRESSURE DEPENDENCE
THERMODYNAMICS
CHEMICAL COATING
DEPOSITION
EPITAXY
HALIDES
HALOGEN COMPOUNDS
IODINE COMPOUNDS
PHASE TRANSFORMATIONS
SURFACE COATING
360602* - Other Materials- Structure & Phase Studies