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Title: CP/MAS /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state

Abstract

Solid-state cross-polarization, magic-angle sample spinning carbon-13 nuclear magnetic resonance spectra have been recorded on chlorophyll a- water aggregates, methyl pyrochlorophyllide a and methyl pyropheophorbide a (derivatives that lack a phytyl chain). Spectra have also been collected under a decoupling regime in which resonances of certain hydrogen-bearing carbon atoms are suppressed. These observations are used to assign the solid state spectra.

Authors:
; ; ;
Publication Date:
Research Org.:
Medical Coll. of Wisconsin, Milwaukee (USA); Nicolet Analytical Corp., Madison, WI (USA); Argonne National Lab., IL (USA)
OSTI Identifier:
5672856
Report Number(s):
DOE/NBM-4000571
ON: DE84000571
DOE Contract Number:  
W-31-109-ENG-38
Resource Type:
Technical Report
Country of Publication:
United States
Language:
English
Subject:
59 BASIC BIOLOGICAL SCIENCES; CARBON 13; NMR SPECTRA; CHLOROPHYLL; BENZENE; CHEMICAL SHIFT; NUCLEAR MAGNETIC RESONANCE; SOLUTIONS; TETRAHYDROFURAN; AROMATICS; CARBON ISOTOPES; CARBOXYLIC ACIDS; DISPERSIONS; EVEN-ODD NUCLEI; FURANS; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; ISOTOPES; LIGHT NUCLEI; MAGNETIC RESONANCE; MIXTURES; NUCLEI; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; ORGANIC OXYGEN COMPOUNDS; PHYTOCHROMES; PIGMENTS; PORPHYRINS; RESONANCE; SPECTRA; STABLE ISOTOPES; 550200* - Biochemistry

Citation Formats

Brown, C.E., Spencer, R.B., Burger, V.T., and Katz, J.J. CP/MAS /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state. United States: N. p., 1983. Web.
Brown, C.E., Spencer, R.B., Burger, V.T., & Katz, J.J. CP/MAS /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state. United States.
Brown, C.E., Spencer, R.B., Burger, V.T., and Katz, J.J. Thu . "CP/MAS /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state". United States.
@article{osti_5672856,
title = {CP/MAS /sup 13/C NMR spectroscopic study of chlorophyll a in the solid state},
author = {Brown, C.E. and Spencer, R.B. and Burger, V.T. and Katz, J.J.},
abstractNote = {Solid-state cross-polarization, magic-angle sample spinning carbon-13 nuclear magnetic resonance spectra have been recorded on chlorophyll a- water aggregates, methyl pyrochlorophyllide a and methyl pyropheophorbide a (derivatives that lack a phytyl chain). Spectra have also been collected under a decoupling regime in which resonances of certain hydrogen-bearing carbon atoms are suppressed. These observations are used to assign the solid state spectra.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Thu Sep 01 00:00:00 EDT 1983},
month = {Thu Sep 01 00:00:00 EDT 1983}
}

Technical Report:
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