Selective hydrogenation of dienes and alkynes to alkenes in the presence of products of the reaction of bis-. pi. -allylpalladium chloride with amines
Journal Article
·
· Kinet. Catal. (Engl. Transl.); (United States)
OSTI ID:5659633
The authors have shown that the interaction of bis-..pi..-allylpalladium chloride with primary or secondary amines containing alkyl groups of substantial size (octyl- or dioctylamine) in toluene medium leads to the formation of palladium complexes active in the homogeneous catalytic hydrogenation of unsaturated hydrocarbons.
- Research Organization:
- A. V. Topchiev Institute of Petrochemical Synthesis, Moscow, USSR
- OSTI ID:
- 5659633
- Journal Information:
- Kinet. Catal. (Engl. Transl.); (United States), Vol. 27:6; Other Information: Translated from Kinet. Katal.; 27: No. 6, 1509-1510(Nov-Dec 1986)
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKYNES
HOMOGENEOUS CATALYSIS
HYDROGENATION
DIENES
PALLADIUM CHLORIDES
CATALYTIC EFFECTS
PALLADIUM COMPLEXES
ALKENES
AMINES
CATALYSTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
COMPLEXOMETRY
TOLUENE
ALKYLATED AROMATICS
AROMATICS
CATALYSIS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
PALLADIUM COMPOUNDS
POLYENES
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ALKYNES
HOMOGENEOUS CATALYSIS
HYDROGENATION
DIENES
PALLADIUM CHLORIDES
CATALYTIC EFFECTS
PALLADIUM COMPLEXES
ALKENES
AMINES
CATALYSTS
CHEMICAL REACTION KINETICS
CHEMICAL REACTION YIELD
COMPLEXOMETRY
TOLUENE
ALKYLATED AROMATICS
AROMATICS
CATALYSIS
CHEMICAL REACTIONS
CHLORIDES
CHLORINE COMPOUNDS
COMPLEXES
HALIDES
HALOGEN COMPOUNDS
HYDROCARBONS
KINETICS
ORGANIC COMPOUNDS
PALLADIUM COMPOUNDS
POLYENES
REACTION KINETICS
TRANSITION ELEMENT COMPLEXES
TRANSITION ELEMENT COMPOUNDS
YIELDS
400201* - Chemical & Physicochemical Properties