Mechanistic studies related to the metal catalyzed reduction of carbon monoxide to hydrocarbons. Progress report, April 1, 1980-January 31, 1982. [Crystal structures of metal formyl and acetyl compounds N (CH/sub 2/CH/sub 3/)/sub 4//sup +/ (CO)/sub 3/((C/sub 6/H/sub 5/O)/sub 3/P)FeCOR/sup -/ were R = H, CH/sub 3/]

Technical Report · Fri Jan 01 00:00:00 EST 1982

OSTI ID:5647874

Casey, C P

The crystal structures of analogous metal formyl and metal acetyl complexes have been determined and the differences analyzed. New heterobimetallic compounds have been prepared for study as possible carbon monoxide hydrogenation catalysts. The synthesis of related bridging methyl, methylene, and methylidyne complexes has been achieved. Several new types of reversible chemical reactions have been discovered including eta/sup 5/-C/sub 5/H/sub 5/ yields eta/sup 1/-C/sub 5/H/sub 5/ rearrangements and addition of C-H bonds to alkenes.

• Research Organization: Wisconsin Univ., Madison (USA)
• DOE Contract Number: AS02-77ER04222
• OSTI ID: 5647874
• Report Number(s): DOE/ER/04222-4; ON: DE82009796
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
10 SYNTHETIC FUELS
CARBON MONOXIDE
METHANATION
REDUCTION
CATALYSTS
RESEARCH PROGRAMS
SYNTHESIS
COBALT COMPLEXES
IRON COMPLEXES
CHEMICAL REACTIONS
CRYSTAL STRUCTURE
MANGANESE COMPLEXES
RHENIUM COMPLEXES
ACETYL RADICALS
COMPLEXES
FORMYL RADICALS
ORGANIC ARSENIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANIC PHOSPHORUS COMPOUNDS
REACTION INTERMEDIATES
ACYL RADICALS
ARSENIC COMPOUNDS
CARBON COMPOUNDS
CARBON OXIDES
CHALCOGENIDES
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
RADICALS
TRANSITION ELEMENT COMPLEXES
010404* - Coal
Lignite
& Peat- Gasification
400301 - Organic Chemistry- Chemical & Physicochemical Properties- (-1987)
090121 - Hydrocarbon Fuels- Chemical Synthesis- (1976-1989)