Synthesis, characterization, and structure of a uranyl complex with a disulfide ligand, Bis(di-n-propylammonium) Disulfidobis(di-n-propylthiocarbamato)dioxouranate(VI)
Olive green crystals of the title compound, ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2//sup +/)/sub 2/(UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 2/NCOS)/sub 2/(S/sub 2/))/sup 2 -/, are orthorhombic, space group Pcan, with a = 15.326 (6) A, b = 17.474 (6) A, c = 14.728 (6) A, and Z = 4 (d/sub x/ = 1.45 g/cm/sup 3/). For 1833 data, I > sigma/sub I/, R = 0.052, and R/sub w/ = 0.069. The structure was revealed by single-crystal x-ray diffraction studies to consist of ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2/)/sup +/ cations and (UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 2/NCOS)/sub 2/(S/sub 2/))/sup 2 -/ anions with the uranium atom at the center of an irregular hexagonal bipyramid. The uranyl oxygen atoms occupy the axial positions. The equatorial coordiantion plane contains the disulfide (S/sub 2//sup 2 -/) group bonded in a side-on fashion and two oxygen and two sulfur donor atoms from the monothiocarbamate ligands. Interatomic distances are S-S = 2.05 (1) A and U-S = 2.711 (3) A (disulfide), U-S = 2.873 (3) A and U-O = 2.48 (1) A (thiocarbamate), and U-0 = 1.82 (1) A (uranyl). The nitrogen atom in the dipropylammonium cation is hydrogen bonded to the uranyl oxygen atoms.
- OSTI ID:
- 5589109
- Journal Information:
- Inorg. Chem.; (United States), Vol. 21:1
- Country of Publication:
- United States
- Language:
- English
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Synthesis and structure of the first actinide disulfur complex, bis(di-n-propylammonium) disulfur bis(di-n-propylmonothiocarbamato)dioxouranate(VI), ((n-C/sub 3/H/sub 7/)/sub 2/NH/sub 2/)/sub 2/(UO/sub 2/((n-C/sub 3/H/sub 7/)/sub 7/NCOS)/sub 2/(S/sub 2/))
Structure of diethylammonium ethoxybis(diethylmonothiocarbamato)dioxouranate(VI), (C/sub 2/H/sub 5/)/sub 2/NH/sub 2//sup +/(UO/sub 2/((C/sub 2/H/sub 5/)/sub 2/NCOS)/sub 2/OC/sub 2/H/sub 5/)/sup -1/
Related Subjects
URANYL COMPLEXES
CRYSTAL STRUCTURE
MOLECULAR STRUCTURE
SYNTHESIS
AMMONIUM COMPOUNDS
BOND ANGLE
CARBONATES
EXPERIMENTAL DATA
INTERATOMIC DISTANCES
LIGANDS
ORGANIC OXYGEN COMPOUNDS
ORGANIC SULFUR COMPOUNDS
SULFIDES
X-RAY DIFFRACTION
ACTINIDE COMPLEXES
CARBON COMPOUNDS
CHALCOGENIDES
COHERENT SCATTERING
COMPLEXES
DATA
DIFFRACTION
DISTANCE
INFORMATION
NUMERICAL DATA
ORGANIC COMPOUNDS
OXYGEN COMPOUNDS
SCATTERING
SULFUR COMPOUNDS
URANIUM COMPLEXES
400702* - Radiochemistry & Nuclear Chemistry- Properties of Radioactive Materials